Metal-doped carbon-supported/modified titanate nanotubes for perfluorooctane sulfonate degradation in water: Effects of preparation conditions, mechanisms, and parameter optimization.

Metal-doped, activated carbon (AC) supported titanate nanotubes (Me/TNTs@AC) have been shown promising for photocatalytic degradation of per- and polyfluoroalkyl substances (PFAS). However, the preparation recipe of the adsorptive photocatalysts has not yet been optimized in terms of type and content of precursor ACs and the metal dopants as well as synthesizing conditions. In this work, the photocatalytic performance of Me/TNTs@AC was evaluated based on the effectiveness in defluorination of pre-sorbed perfluorooctane sulfonic acid (PFOS) after 4-h UV irradiation. Based on the experimental results, the highest photocatalytic mineralization efficiency (66.2 %) of PFOS was achieved using Ga/TNTs@AC prepared under the following conditions: Filtrosorb-400® = 50 wt%, Ga = 2 wt%, hydrothermal treatment temperature = 130 °C, hydrothermal duration = 72 h, and calcination temperature = 550 °C. To understand the underlying mechanisms, selected materials were characterized via X-ray diffraction, the BET surface area and pore volume, UV-vis diffuse reflectance spectrometry, and photoluminescence. The results revealed that the superior photoactivity of Ga/TNTs@AC is attributed to the Ga-facilitated formation of pure crystallized anatase phase during the calcination, high UV light absorption, formation of microscale hybrid AC-anatase-Ga phases, and oxygen defects induced by Ga. The information can facilitate preparation and optimization of composite photocatalysts for efficient adsorption and photocatalytic degradation of PFAS in water.