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纳米粘土水滑石对活性和直接纺织染料回收的最佳浓度。

The Optimal Concentration of Nanoclay Hydrotalcite for Recovery of Reactive and Direct Textile Colorants.

机构信息

Departamento de Ingeniería Textil y Papelera, Universitat Politècnica de València, Plaza Ferrándiz y Carbonell s/n, CP 03801 Alcoy, Spain.

Departamento de Ingeniería Gráfica, Universitat Politècnica de València Plaza Ferrándiz y Carbonell s/n, CP 03801 Alcoy, Spain.

出版信息

Int J Mol Sci. 2022 Aug 26;23(17):9671. doi: 10.3390/ijms23179671.

DOI:10.3390/ijms23179671
PMID:36077071
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9456399/
Abstract

Concerns about the health of the planet have grown dramatically, and the dyeing sector of the textile industry is one of the most polluting of all industries. Nanoclays can clean dyeing wastewater using their adsorption capacities. In this study, as a new finding, it was possible to analyze and quantify the amount of metal ions substituted by anionic dyes when adsorbed, and to determine the optimal amount of nanoclay to be used to adsorb all the dye. The tests demonstrated the specific amount of nanoclay that must be used and how to optimize the subsequent processes of separation and processing of the nanoclay. Hydrotalcite was used as the adsorbent material. Direct dyes were used in this research. X-ray diffraction (XRD) patterns allowed the shape recovery of the hydrotalcite to be checked and confirmed the adsorption of the dyes. An FTIR analysis was used to check the presence of characteristic groups of the dyes in the resulting hybrids. The thermogravimetric (TGA) tests corroborated the dye adsorption and the thermal fastness improvement. Total solar reflectance (TSR) showed increased radiation protection for UV-VIS-NIR. Through the work carried out, it has been possible to establish the maximum adsorption point of hydrotalcite.

摘要

人们对地球健康的担忧与日俱增,而纺织业的染色环节是所有行业中污染最严重的环节之一。纳米粘土可以利用其吸附能力净化染色废水。在这项研究中,作为一项新发现,我们可以分析和量化被阴离子染料吸附时取代的金属离子的数量,并确定吸附所有染料所需的最佳纳米粘土用量。测试证明了必须使用的纳米粘土的具体数量以及如何优化随后的纳米粘土分离和处理过程。水滑石被用作吸附材料。在这项研究中使用了直接染料。X 射线衍射(XRD)图谱允许检查和确认水滑石的形状恢复以及染料的吸附。傅里叶变换红外(FTIR)分析用于检查所得混合物中染料特征基团的存在。热重(TGA)测试证实了染料的吸附以及热稳定性的提高。总太阳反射率(TSR)显示出在 UV-VIS-NIR 范围内的辐射防护增加。通过开展的工作,已经可以确定水滑石的最大吸附点。

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