Kuterasiński Łukasz, Wojtkiewicz Agnieszka M, Sadowska Marta, Żeliszewska Paulina, Napruszewska Bogna D, Zimowska Małgorzata, Pytlik Mateusz, Biessikirski Andrzej
Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, 8 Niezapominajek Street, 30-239 Krakow, Poland.
Conformity Assessment Body, Central Mining Institute, 1 Gwarków Square, 40-166 Katowice, Poland.
Materials (Basel). 2022 Aug 25;15(17):5855. doi: 10.3390/ma15175855.
In the presented research, we investigated Ammonium Nitrate Fuel Oil (ANFO), with the addition of variously modified zeolite Y as an attractive explosive. Analysis of both blasting tests and thermodynamic models of blasting properties led to the conclusion that the addition of zeolite Y enhanced the detonation properties of such prepared ANFO via the growth of the detonation pressure, temperature, compression energy, and heat of the explosion. Generally, the modification of ANFO with variously prepared zeolite Y also reduced the volume of (CO + NO) post-blast fumes. Furthermore, it was found that the ANFO's velocity of detonation (VOD) could be controlled by the choice of the way of zeolite Y modification. Namely, for zeolite Y without Mg, as well as Mg-Y prepared via the impregnation method, the VOD rose. The opposite effect was observed when ANFO was modified with Mg-Y, obtained from the deposition of Mg over zeolite Y via the ultrasonic-assisted procedure.
在本研究中,我们研究了添加各种改性Y型沸石的硝酸铵燃油(ANFO)作为一种有吸引力的炸药。通过爆破试验分析和爆破性能的热力学模型得出结论,添加Y型沸石通过提高爆轰压力、温度、压缩能和爆炸热,增强了这种制备的ANFO的爆轰性能。一般来说,用各种制备的Y型沸石对ANFO进行改性也减少了爆炸后(CO + NO)烟雾的体积。此外,还发现可以通过选择Y型沸石的改性方式来控制ANFO的爆速(VOD)。具体而言,对于不含镁的Y型沸石以及通过浸渍法制备的镁-Y型沸石,VOD会升高。当用通过超声辅助程序在Y型沸石上沉积镁得到的镁-Y型沸石对ANFO进行改性时,观察到相反的效果。