Mauricio F G M, Pralon A Z, Talhavini M, Rodrigues M O, Weber I T
LIMA, Chemistry Institute, University of Brasília-UnB, P.O. Box 04478, 70904-970 Brasília, Brazil.
National Institute of Criminalistics, Brazilian Federal Police, SAIS Quadra 07 Lote 23, 70610-200 Brasília, Brazil.
Forensic Sci Int. 2017 Jun;275:8-13. doi: 10.1016/j.forsciint.2017.02.029. Epub 2017 Mar 6.
This work describes the incorporation of luminescent taggants in cartridges of ammonium nitrate-fuel oil (ANFO) to allow easy identification and collection of post-blast residues. Metal-Organic Frameworks taggants proved to be appropriate for explosive marking when ANFO proportions were above 3.0wt.%. Lanthanide-based light emission enabled in situ retrieval of explosive residues as well as chemical identification, allowing the creation of a coding system using Energy Dispersive Spectroscopy (EDS). The proposed method will accelerate laboratory analysis and support forensic investigations, connecting evidence to suspects and/or to the explosive origin.
这项工作描述了将发光标记物掺入硝酸铵-燃料油(ANFO)药筒中,以便于识别和收集爆炸后的残留物。当ANFO比例高于3.0wt.%时,金属有机框架标记物被证明适用于爆炸物标记。基于镧系元素的发光能够原位获取爆炸物残留物并进行化学识别,从而允许使用能量色散光谱(EDS)创建编码系统。所提出的方法将加速实验室分析并支持法医调查,将证据与嫌疑人及/或爆炸物来源联系起来。