Zhao Yuzhen, Liu Xinhua, Li Qing, Guo Zhun, He Zemin, Zhang Huimin, Ma Cheng, Gao Jianjing, Zhao Yang, Wang Dong
Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi'an 710123, China.
Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Molecules. 2022 Aug 29;27(17):5551. doi: 10.3390/molecules27175551.
Some conjugated benzene ring molecules were prepared using the Sonogashira reaction, and the molecules were post-functionally modified using click chemistry. The optical and electrical band gaps were measured using UV-VIS absorption spectroscopy and the three-electrode method, and the results of both were verified against each other to prove the accuracy of the characterization. In addition, the optical performances of the material were studied by z-scan; almost all materials exhibited good nonlinear optical properties and interconversion between saturable and anti-saturable absorption due to the invocation of click reagents.
使用Sonogashira反应制备了一些共轭苯环分子,并通过点击化学对这些分子进行了后功能修饰。使用紫外可见吸收光谱和三电极法测量了光学和电子带隙,并将两者的结果相互验证以证明表征的准确性。此外,通过z扫描研究了该材料的光学性能;由于引入了点击试剂,几乎所有材料都表现出良好的非线性光学性质以及饱和吸收和反饱和吸收之间的相互转换。