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螺旋藻与稻壳、椰子壳和高密度聚乙烯的水热共液化制备生物原油。

A hydrothermal co-liquefaction of spirulina platensis with rice husk, coconut shell and HDPE for biocrude production.

机构信息

Department of Chemical Engineering, National Institute of Technology Calicut, Kozhikode 673601, India.

Department of Chemical Engineering, National Institute of Technology Calicut, Kozhikode 673601, India.

出版信息

Bioresour Technol. 2022 Nov;363:127911. doi: 10.1016/j.biortech.2022.127911. Epub 2022 Sep 8.

DOI:10.1016/j.biortech.2022.127911
PMID:36089126
Abstract

Hydrothermal liquefaction (HTL) is a thermochemical conversion process to produce biofuel from biomass. In this work, co-HTL of spirulina platensis (SP) with rice husk (RH), coconut shell (CS) and high-density polyethylene (HDPE) is performed, which are not reported in the literature. The maximum biocrude yield for SP and RH mixture is 20.1 wt% at blend ratio of 50:50, temperature of 300 °C, reaction time of 30 mins and solid loading of 20 wt% whereas for SP and CS mixture, the maximum biocrude yield of 12.2 wt% is obtained under same operating conditions. It is found that biocrude yield enhances with increasing blending ratio of SP to lignocellulosic biomass. For co-HTL of SP and HDPE, the maximum biocrude yield of 28.8 wt% is obtained at blend ratio of 50:50, 350 °C, 30 mins and 20 wt% solid concentrations. For this case, the biocrude yield decreases with increasing SP/HDPE ratios. Furthermore, various characterisation methods are used to analyse the quality of biocrude.

摘要

水热液化(HTL)是一种将生物质转化为生物燃料的热化学转化工艺。在这项工作中,我们对螺旋藻(SP)与稻壳(RH)、椰子壳(CS)和高密度聚乙烯(HDPE)进行共 HTL,这在文献中尚未报道。在混合比例为 50:50、温度为 300°C、反应时间为 30 分钟和固载量为 20wt%的条件下,SP 和 RH 混合物的最大生物油产率为 20.1wt%,而对于 SP 和 CS 混合物,在相同操作条件下,最大生物油产率为 12.2wt%。研究发现,生物油产率随 SP 与木质纤维素生物质混合比例的增加而提高。对于 SP 和 HDPE 的共 HTL,在混合比例为 50:50、350°C、30 分钟和 20wt%固载量的条件下,最大生物油产率为 28.8wt%。在这种情况下,生物油产率随 SP/HDPE 比例的增加而降低。此外,还采用了各种特性分析方法来分析生物油的质量。

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