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使用具有陶瓷结构的太赫兹时域光谱技术进行太赫兹气体传感

THz Gas Sensing Using Terahertz Time-Domain Spectroscopy with Ceramic Architecture.

作者信息

Komatsu Keiji, Iwamoto Toshiyuki, Ito Haruhiko, Saitoh Hidetoshi

机构信息

Department of Materials Science and Bioengineering, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188, Japan.

NIPPO PRECISION Co. Ltd., Nirasaki, Yamanashi 407-0175, Japan.

出版信息

ACS Omega. 2022 Aug 25;7(35):30768-30772. doi: 10.1021/acsomega.2c01635. eCollection 2022 Sep 6.

Abstract

Ceramic architectures based on chemical vapor deposition (CVD) are used to create unique crystal structures, morphologies, and properties. This study proposed room-temperature THz gas sensing using terahertz time-domain spectroscopy (THz-TDS) with ceramic architectures. We synthesized ceramic films on porous glass. Zinc oxide films were created using atmospheric CVD and amorphous carbon nitride films using the dissociative excitation reaction of BrCN with metastable Ar atoms. The transmission method was used in THz-TDS. A stainless hand-made gas cell with a Si window was applied for THz gas sensing. We defined "phase delay" equals VOC sensing response amount of sensing materials at each duration. Ppm-order THz gas sensing was performed.

摘要

基于化学气相沉积(CVD)的陶瓷结构用于创建独特的晶体结构、形态和性能。本研究提出了利用太赫兹时域光谱(THz-TDS)结合陶瓷结构进行室温太赫兹气体传感。我们在多孔玻璃上合成了陶瓷薄膜。使用常压化学气相沉积法制备了氧化锌薄膜,并利用BrCN与亚稳态Ar原子的离解激发反应制备了非晶态氮化碳薄膜。太赫兹时域光谱采用透射法。一个带有硅窗的不锈钢手工制作气室被用于太赫兹气体传感。我们将“相位延迟”定义为每种持续时间下传感材料的VOC传感响应量。进行了ppm级的太赫兹气体传感。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cc0/9453963/2fa2b937af56/ao2c01635_0002.jpg

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