He Pin-Jing, Li Jian-Chen, Lü Fan, Zhang Hua, Shao Li-Ming
College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China.
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China.
Huan Jing Ke Xue. 2022 Sep 8;43(9):4506-4512. doi: 10.13227/j.hjkx.202107035.
In order to explore the source characteristics as well as the temporal and spatial variations in odor pollution in municipal waste landfills, gas samples were collected from a landfill in an eastern coastal area of China throughout winter and summer. The total concentration of malodorous substances reached 60000 μg·m. There were more types of odor pollutants detected in summer than in winter, the average concentration was 30-300 times higher than that in winter, and the concentration of sulfur compounds increased by 4.7-136.7 times in summer. Oxygenated compounds had the highest concentration, and the total concentration of sulfur compounds accounted for less than 10% of malodorous substances. However, sulfur compounds contributed more than 90% to the theoretical odor concentration. Sulfur compounds such as methyl mercaptan and propane mercaptan were the key odorants in the landfill. After the landfill unit was covered, the concentration of odorous substances and the theoretical odor concentration on the surface of the landfill showed an increasing trend with time, indicating that the covering had a certain odor barrier effect; however, the landfill unit still had a large odor release potential. The similarity analysis showed that the odorous gas accumulated in the unit with temporary cover and without an exhaust system could be released to the environment through the overlapping gap of the membrane and the location of membrane rupture, resulting in more serious odor pollution around the landfill at night than that during the day.
为探究城市垃圾填埋场臭气污染的源特征以及时空变化规律,于冬夏两季对中国东部沿海某垃圾填埋场进行气体采样。恶臭物质总浓度达60000μg·m 。夏季检出的臭气污染物种类多于冬季,平均浓度比冬季高30 - 300倍,夏季含硫化合物浓度升高4.7 - 136.7倍。含氧有机物浓度最高,含硫化合物总浓度占恶臭物质的比例不到10%。但含硫化合物对理论臭气浓度的贡献超过90%。甲硫醇、丙硫醇等含硫化合物是填埋场关键臭气成分。垃圾填埋单元覆盖后,填埋场表面臭气物质浓度及理论臭气浓度随时间呈上升趋势,表明覆盖具有一定的臭气阻隔作用;然而,填埋单元仍有较大的臭气释放潜力。相似性分析表明,临时覆盖且无排气系统的单元内积聚的臭气可通过膜的搭接缝隙及膜破损处释放到环境中,导致填埋场周边夜间臭气污染比白天更严重。