ASAS, Amity University Rajasthan, Jaipur, 303002, India.
Amity University Rajasthan, Jaipur, 303002, India.
Top Curr Chem (Cham). 2022 Sep 16;380(6):48. doi: 10.1007/s41061-022-00402-9.
Enantioselective synthesis through photocatalysis is one of the highly preferred approaches towards preparation of optically active compounds. This review elaborates and critically analyzes the different strategies of photocatalytic enantioselective reactions through H-bonding, transition metal catalysis, phase-transfer catalysis (PTC), chiral Lewis acid catalysis, N-heterocyclic carbene catalysis, and amine catalysis, and also explores ion pairs. In addition, it explains the different catalysis modes with multifunctional approaches for enantioselective photocatalytic reactions.
通过光催化进行对映选择性合成是制备光学活性化合物的首选方法之一。本综述详细阐述和批判性分析了通过氢键、过渡金属催化、相转移催化 (PTC)、手性路易斯酸催化、N-杂环卡宾催化和胺催化进行光催化对映选择性反应的不同策略，并探讨了离子对。此外，它还解释了用于对映选择性光催化反应的多功能方法的不同催化模式。
