Amin Ihsan, Brekel Hidde van den, Nemani Kartik, Batyrev Erdni, de Vooys Arnoud, van der Weijde Hans, Anasori Babak, Shiju N Raveendran
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands.
Department of Mechanical and Energy Engineering, Purdue School of Engineering and Technology and Integrated Nanosystems Development Institute, Indiana University-Purdue University Indianapolis, Indianapolis, Indiana 46202, United States.
ACS Appl Mater Interfaces. 2022 Sep 28;14(38):43749-43758. doi: 10.1021/acsami.2c11953. Epub 2022 Sep 19.
As the most studied two-dimensional (2D) material from the MXene family, TiCT has constantly gained interest from academia and industry. TiCT MXene has the highest electrical conductivity (up to 24,000 S cm) and one of the highest stiffness values with a Young's modulus of ∼ 334 GPa among water-dispersible conductive 2D materials. The negative surface charge of MXene helps to disperse it well in aqueous and other polar solvents. This solubility across a wide range of solvents, excellent interface interaction, tunable surface functionality, and stability with other organic/polymeric materials combined with the layered structure of TiCT MXene make it a promising material for anticorrosion coatings. While there are many reviews on TiCT MXene polymer composites for catalysis, flexible electronics, and energy storage, to our knowledge, no review has been published yet on MXenes' anticorrosion applications. In this brief report, we summarize the current progress and the development of TiCT polymer composites for anticorrosion. We also provide an outlook and discussion on possible ways to improve the exploitation of TiCT polymer composites as anticorrosive materials. Finally, we provide a perspective beyond TiCT MXene composition for the development of future anticorrosion coatings.
作为来自MXene家族研究最多的二维(2D)材料,TiCT一直受到学术界和工业界的关注。TiCT MXene具有最高的电导率(高达24,000 S/cm),并且在水分散性导电二维材料中具有最高的刚度值之一,杨氏模量约为334 GPa。MXene的负表面电荷有助于其在水性和其他极性溶剂中良好分散。TiCT MXene在广泛的溶剂中的溶解性、优异的界面相互作用、可调节的表面功能以及与其他有机/聚合物材料的稳定性,再加上其层状结构,使其成为用于防腐涂层的有前途的材料。虽然有许多关于TiCT MXene聚合物复合材料用于催化、柔性电子和能量存储的综述,但据我们所知,尚未有关于MXenes防腐应用的综述发表。在这份简短的报告中,我们总结了TiCT聚合物复合材料在防腐方面的当前进展和发展情况。我们还对改进TiCT聚合物复合材料作为防腐材料的开发的可能方法进行了展望和讨论。最后,我们为未来防腐涂层的发展提供了超越TiCT MXene组成的观点。