Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710119, Xi'an, P. R. China.
ChemSusChem. 2022 Nov 8;15(21):e202201788. doi: 10.1002/cssc.202201788. Epub 2022 Oct 5.
In this series of articles, the Board Members of ChemSusChem review recent research articles that they consider of exceptional quality and importance for sustainability. This entry features Prof. Rui Cao, who discusses how tuning the second-sphere environments of Fe porphyrins can improve the activity and selectivity for CO reduction. Substituents with proton relay capability, hydrogen-bonding, and electrostatic features have significant impact on the efficiency of Fe porphyrins for the electrocatalytic CO reduction reaction.
在本系列文章中，ChemSusChem 的理事会成员回顾了他们认为具有特殊质量和重要性的可持续性研究文章。这篇文章的特色是曹睿教授，他讨论了如何调整 Fe 卟啉的第二球环境可以提高 CO 还原的活性和选择性。具有质子传递能力、氢键和静电特性的取代基对 Fe 卟啉电催化 CO 还原反应的效率有重大影响。
