Wang Shuxin, Xiong Lin, Sun Guodong, Tang Li, Zhang Jun, Pei Yong, Zhu Manzhou
Department of Chemistry, Center for Atomic Engineering of Advanced Materials, Anhui University Hefei Anhui 230601 PR China
Department of Chemistry, Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, Xiangtan University Xiangtan Hunan 411105 PR China
Nanoscale Adv. 2020 Jan 14;2(2):664-668. doi: 10.1039/c9na00746f. eCollection 2020 Feb 18.
We substituted gold atoms in fcc structured Au and Au nanoclusters with a Ag(i)SR complex and obtained Ag Au and Ag Au nanoclusters, respectively. The positive electrostatic potential (ESP) and dual descriptor (Δ) values were calculated for the metal cores of both nanoclusters, which indicated that the metal exchange is an electrophilic reaction.
我们用Ag(i)SR配合物取代了面心立方结构的Au和Au纳米团簇中的金原子，分别得到了Ag@Au和Ag@Au纳米团簇。计算了两种纳米团簇金属核的正静电势(ESP)和双描述符(Δ)值，结果表明金属交换是一种亲电反应。
