Romani Alessia, Tralli Paolo, Levi Marinella, Turri Stefano, Suriano Raffaella
Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, Italy.
Design Department, Politecnico di Milano, Via Durando 10, 20158 Milano, Italy.
Materials (Basel). 2022 Sep 8;15(18):6242. doi: 10.3390/ma15186242.
An ever-growing amount of composite waste will be generated in the upcoming years. New circular strategies based on 3D printing technologies are emerging as potential solutions although 3D-printed products made of recycled composites may require post-processing. Metallization represents a viable way to foster their exploitation for new applications. This paper shows the use of physical vapor deposition sputtering for the metallization of recycled glass fiber-reinforced polymers processed by UV-assisted 3D printing. Different batches of 3D-printed samples were produced, post-processed, and coated with a chromium metallization layer to compare the results before and after the metallization process and to evaluate the quality of the finishing from a qualitative and quantitative point of view. The analysis was conducted by measuring the surface gloss and roughness, analyzing the coating morphology and thickness through the Scanning Electron Microscopy (SEM) micrographs of the cross-sections, and assessing its adhesion with cross-cut tests. The metallization was successfully performed on the different 3D-printed samples, achieving a good homogeneity of the coating surface. Despite the influence of the staircase effect, these results may foster the investigation of new fields of application, as well as the use of different polymer-based composites from end-of-life products, i.e., carbon fiber-reinforced polymers.
在未来几年,复合废料的产生量将不断增加。基于3D打印技术的新型循环利用策略正在成为潜在的解决方案,尽管由回收复合材料制成的3D打印产品可能需要进行后处理。金属化是促进其在新应用中得到利用的一种可行方法。本文展示了利用物理气相沉积溅射对通过紫外线辅助3D打印加工的回收玻璃纤维增强聚合物进行金属化处理。制作了不同批次的3D打印样品,进行后处理,并涂上铬金属化层,以比较金属化处理前后的结果,并从定性和定量的角度评估表面处理的质量。通过测量表面光泽度和粗糙度、通过横截面的扫描电子显微镜(SEM)显微照片分析涂层形态和厚度以及通过划格试验评估其附着力来进行分析。在不同的3D打印样品上成功进行了金属化处理,涂层表面实现了良好的均匀性。尽管有阶梯效应的影响,但这些结果可能会促进对新应用领域的研究,以及对来自报废产品的不同聚合物基复合材料(即碳纤维增强聚合物)的使用。