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漆酶催化合成木质素水凝胶的工艺开发、技术经济分析及生命周期评估

Process development, techno-economic analysis and life-cycle assessment for laccase catalyzed synthesis of lignin hydrogel.

作者信息

Gujjala Lohit Kumar Srinivas, Won Wangyun

机构信息

Department of Chemical Engineering (Integrated Engineering), Kyung Hee University, 1732, Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, Republic of Korea.

Department of Chemical Engineering (Integrated Engineering), Kyung Hee University, 1732, Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, Republic of Korea.

出版信息

Bioresour Technol. 2022 Nov;364:128028. doi: 10.1016/j.biortech.2022.128028. Epub 2022 Sep 26.

Abstract

In this study, an effort has been undertaken to study process design, techno-economic analysis, and life-cycle assessment (LCA) of lignin hydrogel (LH) which has potential applications in environmental remediation. Minimum selling price (MSP) of LHs has been estimated to be 2,141 US$/ton and it lies within the range of market price (1,420-2,280 US$/ton) for commercial coagulants. Further, sensitivity analysis has been conducted and it was observed that "% efficiency of lignin hydrogel production" and "lignin price" were the most influential parameters. Uncertainty analysis has also been conducted to study the influence of volatility in the market price of lignin and total capital investment on MSP of LH. From LCA study, it was estimated that the proposed process will emit 2.8 kg CO eq. and 1.1 kg Oil eq./kg lignin hydrogel. The developed process can be utilized for lignin upgradation in biorefineries to develop economically feasible and sustainable processes.

摘要

在本研究中,已开展工作来研究木质素水凝胶(LH)的工艺设计、技术经济分析和生命周期评估(LCA),其在环境修复方面具有潜在应用。木质素水凝胶的最低售价估计为2141美元/吨,处于商业混凝剂市场价格(1420 - 2280美元/吨)范围内。此外,进行了敏感性分析,结果表明“木质素水凝胶生产效率百分比”和“木质素价格”是最具影响力的参数。还进行了不确定性分析,以研究木质素市场价格波动和总资本投资对木质素水凝胶最低售价的影响。从生命周期评估研究中估计,所提出的工艺将排放2.8千克二氧化碳当量和1.1千克油当量/千克木质素水凝胶。所开发的工艺可用于生物精炼厂中的木质素升级,以开发经济可行且可持续的工艺。

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