Lan Huanshi, Qin Zuzeng, Shi Shaolin, Zhang Xingcong, He Xiaohui, Ji Hongbing
School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China.
Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, Guangdong, China.
Dalton Trans. 2022 Oct 18;51(40):15227-15232. doi: 10.1039/d2dt02075k.
Atomically dispersed Pt species supported on FeO (Pt/FeO) are successfully constructed by a simple ball milling process. In the selective hydrogenation of cinnamaldehyde (CAL), Pt/FeO achieves an excellent cinnamyl alcohol (COL) selectivity of 81.7% at a CAL conversion of 91.2% in pure water medium due to the superior dissociation ability of H and preferential adsorption of CAL CO.
通过简单的球磨工艺成功构建了负载在FeO上的原子分散Pt物种（Pt/FeO）。在肉桂醛（CAL）的选择性加氢反应中，由于H的优异解离能力和CAL CO的优先吸附，Pt/FeO在纯水介质中，当CAL转化率为91.2%时，实现了81.7%的优异肉桂醇（COL）选择性。
