Nanoporous Metal-Organic Framework Thin Films with Embedded Fulgide for Light-Modulated Guest Adsorption and Diffusion.

Smart and photoresponsive materials and thin films allow the dynamic remote control of their central properties. By incorporation of photochromic molecules in nanoporous metal-organic frameworks (MOFs), the interaction between the MOF host and the guest molecules in the pores can be modified. Here, a MOF film of type UiO-68 is presented in which the photoswitchable feature is added by embedment of photochromic fulgide molecules of type Aberchrome 670 in the pores. The photoisomerization in the pores is explored by UV-vis and infrared spectroscopy, and the transient uptake of toluene and methanol probe molecules is explored using a quartz crystal microbalance. For the first time, a fulgide-based nanoporous material is used to remote-control the adsorption and diffusion properties. We find that the toluene uptake amount can be increased by 37% and the toluene diffusion coefficient can be increased by 40% when reversibly photoswitching the embedded fulgide from its -form to -form. In this way, this study aims to contribute to the field of light-responsive nanoporous materials and thus expands the range of smart coatings.