多并苯环取代磷（P、P、P）稠环芳烃的合成、性质及应用的综合评述。

Comprehensive Review on Synthesis, Properties, and Applications of Phosphorus (P, P, P) Substituted Acenes with More Than Two Fused Benzene Rings.

机构信息

Division of Organic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, Poland.

Institute of Chemistry, Faculty of Science and Technology, Jan Długosz University in Częstochowa, Armii Krajowej 13/15, 42-200 Częstochowa, Poland.

出版信息

Molecules. 2022 Oct 5;27(19):6611. doi: 10.3390/molecules27196611.

This comprehensive review, covering the years 1968-2022, is not only a retrospective investigation of a certain group of linearly fused aromatics, called acenes, but also a presentation of the current state of the knowledge on the synthesis, reactions, and applications of these compounds. Their characteristic feature is substitution of the aromatic system by one, two, or three organophosphorus groups, which determine their properties and applications. The (P, P, P) phosphorus atom in organophosphorus groups is linked to the acene directly by a P-C bond or indirectly through an oxygen atom by a P-O-C bond.