Fogašová Mária, Figalla Silvestr, Danišová Lucia, Medlenová Elena, Hlaváčiková Slávka, Vanovčanová Zuzana, Omaníková Leona, Baco Andrej, Horváth Vojtech, Mikolajová Mária, Feranc Jozef, Bočkaj Ján, Plavec Roderik, Alexy Pavol, Repiská Martina, Přikryl Radek, Kontárová Soňa, Báreková Anna, Sláviková Martina, Koutný Marek, Fayyazbakhsh Ahmad, Kadlečková Markéta
Institute of Natural and Synthetic Polymers, Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 812 37 Bratislava, Slovak Republic.
Institute of Materials Science, Faculty of Chemistry, Brno University of Technology, Purkyňova 464/118, 612 00 Brno, Czech Republic.
Polymers (Basel). 2022 Sep 30;14(19):4113. doi: 10.3390/polym14194113.
In order to make bioplastics accessible for a wider spectrum of applications, ready-to-use plastic material formulations should be available with tailored properties. Ideally, these kinds of materials should also be "home-compostable" to simplify their organic recycling. Therefore, materials based on PLA (polylactid acid) and PHB (polyhydroxybutyrate) blends are presented which contain suitable additives, and some of them contain also thermoplastic starch as a filler, which decreases the price of the final compound. They are intended for various applications, as documented by products made out of them. The produced materials are fully biodegradable under industrial composting conditions. Surprisingly, some of the materials, even those which contain more PLA than PHB, are also fully biodegradable under home-composting conditions within a period of about six months. Experiments made under laboratory conditions were supported with data obtained from a kitchen waste pilot composter and from municipal composting plant experiments. Material properties, environmental conditions, and microbiology data were recorded during some of these experiments to document the biodegradation process and changes on the surface and inside the materials on a molecular level.
为了使生物塑料能够应用于更广泛的领域,应提供具有定制特性的即用型塑料材料配方。理想情况下,这类材料还应“家庭可堆肥”,以简化其有机回收。因此,本文介绍了基于聚乳酸(PLA)和聚羟基丁酸酯(PHB)共混物的材料,这些材料含有合适的添加剂,其中一些还含有热塑性淀粉作为填料,这降低了最终化合物的价格。它们适用于各种应用,由其制成的产品即可证明。所生产的材料在工业堆肥条件下可完全生物降解。令人惊讶的是,一些材料,即使是那些PLA含量高于PHB的材料,在家庭堆肥条件下约六个月内也可完全生物降解。实验室条件下的实验得到了来自厨房垃圾试验堆肥器和城市堆肥厂实验数据的支持。在其中一些实验过程中记录了材料特性、环境条件和微生物学数据,以记录生物降解过程以及材料表面和内部在分子水平上的变化。