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含双可裂解键和 AIE 发光团的多功能聚(碳二酰亚胺酯)的合成. 帕斯基尼型多组分聚合反应。

Synthesis of multifunctional poly(carbamoyl ester)s containing dual-cleavable linkages and an AIE luminogen Passerini-type multicomponent polymerization.

机构信息

Department of Chemical Engineering, i-Center for Advanced Science and Technology (iCAST), National Chung Hsing University, Taichung, 40227, Taiwan.

Department of Materials and Optoelectronic Science, Center for Nanoscience and Nanotechnology, National Sun Yat-Sen University, Kaohsiung, 80424, Taiwan.

出版信息

Chem Commun (Camb). 2022 Nov 3;58(88):12317-12320. doi: 10.1039/d2cc03829c.

Abstract

We conducted Passerini-type multicomponent polymerizations (P-MCPs) with various monomers and afforded a series of functional poly(carbamoyl ester)s (PCEs). We demonstrated an efficient, diverse, and facile approach through P-MCPs to produce these novel PCEs with dual-cleavable linkages of ester and disulfide groups and the aggregation-induced emission (AIE) luminogen tetraphenylethylene (TPE).

摘要

我们进行了各种单体的 Passerini 型多组分聚合(P-MCP)反应,得到了一系列功能性聚(氨基甲酸酯)(PCE)。我们通过 P-MCP 展示了一种高效、多样和简便的方法,用于制备这些具有酯和二硫键双可裂解连接基团以及聚集诱导发光(AIE)生色团四苯乙烯(TPE)的新型 PCE。

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