A comprehensive framework for identifying contributing factors of soil trace metal pollution using Geodetector and spatial bivariate analysis.

The accurate identification of pollution sources is important for controlling soil pollution. However, the widely used Positive matrix factorization (PMF) model generally relies on knowledge and experience to accurately identify pollution sources; thus, this method faces significant challenges in objectively identifying soil pollution sources. Herein, we established a comprehensive source analysis framework using factor identification and geospatial analysis, and revealed the factors contributing to trace metal(loid) (TM) pollution in soil in the Pearl River Delta (PRD), China. Using the PMF model, we initially considered that the PRD may be affected by natural, atmospheric, traffic and industrial, and agricultural sources. Moreover, Geodetector model detected the relationship between TMs and 12 environmental variables based on the strong spatial "source-sink" relationship of pollutants. The parent material and digital elevation model were the key factors predicting the accumulation of Cr, Ni, and Cu. Industries and roads were the most important determinants of Pb, Zn, and Cd, whereas atmospheric deposition was more important for Hg accumulation. The accumulation of As was found to be closely related to agricultural activities such as the application of chemical fertilizers and pesticides. The spatial autocorrelation between soil TM pollution and environmental variables further supports this hypothesis. Overall, the obtained results showed that proposed approach improved the accuracy of source apportionment and provided a basis for soil pollution control.