The Advance and Critical Functions of Energetic Carbon Dots in Carbon Dioxide Photo/Electroreduction Reactions.

As a unique carbon-based nano material, carbon dots (CDs) have attracted great attention because of their special structures and properties, and have been widely used in various fields, such as bio-imaging technology, catalyst design, pollutant degradation, chemical analysis, clean energy development and so on. CDs are used as catalysts or cocatalysts for multiple energy conversion reactions due to their advantages of valid visible light utilization, fast transmission of charge carriers, excellent catalytic activity, and good electrical conductivity. This review first summarizes the basic structure and properties of CDs. The advance and critical functions of energetic CDs in carbon dioxide photo/electroreduction reactions are discussed in detail. Due to the excellent optical absorption, electron transfer properties and good conductivity of CDs, they can enhance catalytic activity and stability effectively. In the end, the existing problems and future development opportunities of CDs-based catalysts in CO reduction reaction are proposed and outlined.