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含有花青素的基于西米淀粉的智能包装薄膜的表征及颜色响应

Characterisation and Colour Response of Smart Sago Starch-Based Packaging Films Incorporated with Anthocyanin.

作者信息

Che Hamzah Nurul Husna, Khairuddin Nozieana, Muhamad Ida Idayu, Hassan Mohd Ali, Ngaini Zainab, Sarbini Shahrul Razid

机构信息

Department of Science and Technology, Faculty of Humanities, Management, and Science, Universiti Putra Malaysia, Bintulu Sarawak Campus, Bintulu 97008, Malaysia.

Department of Bioprocess and Polymer Engineering, Universiti Teknologi Malaysia, Johor Bahru 81310, Malaysia.

出版信息

Membranes (Basel). 2022 Sep 21;12(10):913. doi: 10.3390/membranes12100913.

Abstract

To meet the need for food products to be safe and fresh, smart food packaging that can monitor and give information about the quality of packaged food has been developed. In this study, pH-sensitive films with sago starch and various anthocyanin concentrations of also known as red cabbage anthocyanin (RCA) at 8, 10, 12, and 14% (/) were manufactured using the solvent casting process. Investigation of the physicochemical, mechanical, thermal, and morphological characteristics of the films was performed and analysed. The response of these materials against pH changes was evaluated with buffers of different pH. When the films were exposed to a series of pH buffers (pH 3, 5, 9, 11, and 13), the RCA-associated films displayed a spectacular colour response. In addition, the ability of the starch matrix to overcome the leaching and release of anthocyanins was investigated. Higher concentrations of RCA can maintain the colour difference of films after being immersed in a series of buffer solutions ranging from acidic to basic conditions. Other than that, incorporating RCA extracts into the starch formulation increased the thickness whereas the water content, swelling degree, tensile strength, and elongation at break decreased as compared to films without RCA. The immobilisation of anthocyanin into the film was confirmed by the FTIR measurements. The surface patterns of films were heterogeneous and irregular due to the presence of RCA extract aggregates, which increased as the extract concentration enhanced. However, this would not affect the properties of films. An increase in thermal stability was noted for the anthocyanin-containing films at the final stage of degradation in TGA analysis. It is concluded that RCA and sago starch formulation has great potential to be explored for food packaging purposes.

摘要

为满足食品既安全又新鲜的需求,已开发出能够监测并提供包装食品质量信息的智能食品包装。在本研究中,采用溶剂浇铸法制备了含有西米淀粉和不同花青素浓度(8%、10%、12%和14%(/),即红甘蓝花青素(RCA))的pH敏感薄膜。对薄膜的物理化学、机械、热学和形态学特性进行了研究和分析。用不同pH值的缓冲液评估了这些材料对pH变化的响应。当薄膜暴露于一系列pH缓冲液(pH 3、5、9、11和13)时,与RCA相关的薄膜呈现出显著的颜色响应。此外,还研究了淀粉基质克服花青素浸出和释放的能力。较高浓度的RCA在浸入从酸性到碱性的一系列缓冲溶液后,仍能保持薄膜的色差。除此之外,与不含RCA的薄膜相比,将RCA提取物加入淀粉配方中会增加薄膜厚度,而水分含量、溶胀度、拉伸强度和断裂伸长率则会降低。通过傅里叶变换红外光谱(FTIR)测量证实了花青素固定在薄膜中。由于RCA提取物聚集体存在,薄膜的表面图案不均匀且不规则,且随着提取物浓度的增加而增加。然而,这不会影响薄膜的性能。在热重分析(TGA)中,含花青素薄膜在降解的最后阶段热稳定性有所提高。得出的结论是,RCA与西米淀粉配方在食品包装用途方面具有很大的探索潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e073/9607244/d2b8df5c1322/membranes-12-00913-g001.jpg

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