一种用于中性水溶液中电催化水氧化的低成本商业Cu(II)-EDTA配合物。
A low-cost commercial Cu(II)-EDTA complex for electrocatalytic water oxidation in neutral aqueous solution.
作者信息
Yu Kaishan, Sun Yue, Zhu Dingwei, Xu Ziyi, Wang Jiayi, Shen Junyu, Zhang Qijian, Zhao Wei
机构信息
Jiangsu Laboratory of Advanced Functional Materials, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China.
出版信息
Chem Commun (Camb). 2022 Nov 17;58(92):12835-12838. doi: 10.1039/d2cc04846a.
Herein, we choose a commercial Cu complex [Cu(EDTA)(HO)] (EDTA = ethylene diamine tetraacetic acid) as a molecular catalyst for water oxidation to avoid complex synthesis and lower catalyst cost. [Cu(EDTA)(HO)] could catalyze the water oxidation reaction efficiently under neutral conditions with an overpotential of 684 mV, a of 8.03 s and good stability in the long-term electrolysis. Our finding is of great significance for the development of stable, rapid, and easily accessible catalysts for water oxidation.
在此，我们选择一种商业铜配合物[Cu(EDTA)(HO)]（EDTA = 乙二胺四乙酸）作为水氧化的分子催化剂，以避免复杂的合成过程并降低催化剂成本。[Cu(EDTA)(HO)]能够在中性条件下高效催化水氧化反应，过电位为684 mV，周转频率为8.03 s ，并且在长期电解中具有良好的稳定性。我们的发现对于开发稳定、快速且易于获得的水氧化催化剂具有重要意义。
Zotero 插件