基于偶氮苯的非天然氨基酸支架：钯(II)催化的 C(sp2)-H 芳基化策略。
Azobenzene-based unnatural amino acid scaffolds a Pd(II)-catalyzed C(sp)-H arylation strategy.
机构信息
Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Knowledge City, Sector 81, SAS Nagar, Manauli P.O. 140306, Mohali, Punjab, India.
出版信息
Chem Commun (Camb). 2022 Nov 22;58(93):12967-12970. doi: 10.1039/d2cc04870a.
PMID:36322011
Abstract
Azobenzene-based unnatural amino acid motifs were synthesized Pd(II)-catalyzed diastereoselective C(sp)-H arylation of amino acid carboxamides with iodoacetanilides and Mills azo coupling.
摘要
基于偶氮苯的非天然氨基酸基序通过钯（II）催化的氨基酸酰胺与碘乙酰胺和米尔斯偶氮偶联的 C(sp)-H 区域选择性不对称芳基化反应合成。
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