• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

用于电化学CO还原的铜基双金属材料的现状：综述

Current state of copper-based bimetallic materials for electrochemical CO reduction: a review.

作者信息

Zoubir Otmane, Atourki Lahoucine, Ait Ahsaine Hassan, BaQais Amal

机构信息

MANAPSE Lab, Faculty of Sciences, Mohammed V University in Rabat Morocco

Laboratoire de Chimie Appliquée des Matériaux, Faculty of Sciences, Mohammed V University in Rabat Morocco

出版信息

RSC Adv. 2022 Oct 21;12(46):30056-30075. doi: 10.1039/d2ra05385c. eCollection 2022 Oct 17.

DOI:10.1039/d2ra05385c
PMID:36329940
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9585392/
Abstract

The increasing CO concentration in the atmosphere has caused profound environmental issues such as global warming. The use of CO as a feedstock to replace traditional fossil sources holds great promise to reduce CO emissions. The electrochemical conversion of CO has attracted much attention because it can be powered by renewable sources such as solar energy. In this review article, we provide insight into the important parameters when studying CORR and give a comprehensive review on the description of synthesis methods with electrocatalytic CO reduction over bimetallic copper-based materials. Due to the important bibliographic data on Cu bimetallic materials, we have limited this review to Sn, In, Pd, Zn and Ag. At the end of this review, challenges and perspectives for further upgrading have been included to briefly highlight the important future considerations of this rapidly growing technology.

摘要

大气中一氧化碳（CO）浓度的不断增加引发了诸如全球变暖等深刻的环境问题。将CO用作原料以替代传统化石源有望大幅减少CO排放。CO的电化学转化备受关注，因为它可以由太阳能等可再生能源提供动力。在这篇综述文章中，我们深入探讨了研究CO还原反应（CORR）时的重要参数，并全面综述了基于双金属铜材料的电催化CO还原合成方法的描述。由于关于铜双金属材料的重要文献数据，我们将本综述局限于锡（Sn）、铟（In）、钯（Pd）、锌（Zn）和银（Ag）。在本综述结尾，还纳入了进一步升级的挑战和展望，以简要突出这一快速发展技术未来的重要考量因素。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/2fb47cd12070/d2ra05385c-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/a0da6e84fac5/d2ra05385c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/6feb16aa83d3/d2ra05385c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/5161a0334e99/d2ra05385c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/c85f0ac0e3da/d2ra05385c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/cd0adfd90050/d2ra05385c-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/1e93649344a9/d2ra05385c-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/9cf5cda26435/d2ra05385c-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/d58d2d9b4c1d/d2ra05385c-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/a6d0724f9b52/d2ra05385c-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/2fb47cd12070/d2ra05385c-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/a0da6e84fac5/d2ra05385c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/6feb16aa83d3/d2ra05385c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/5161a0334e99/d2ra05385c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/c85f0ac0e3da/d2ra05385c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/cd0adfd90050/d2ra05385c-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/1e93649344a9/d2ra05385c-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/9cf5cda26435/d2ra05385c-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/d58d2d9b4c1d/d2ra05385c-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/a6d0724f9b52/d2ra05385c-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c495/9585392/2fb47cd12070/d2ra05385c-f10.jpg

相似文献

1
Current state of copper-based bimetallic materials for electrochemical CO reduction: a review.用于电化学CO还原的铜基双金属材料的现状：综述
RSC Adv. 2022 Oct 21;12(46):30056-30075. doi: 10.1039/d2ra05385c. eCollection 2022 Oct 17.
2
Bimetallic Electrocatalysts for CO Reduction.双金属电催化剂用于 CO 还原。
Top Curr Chem (Cham). 2018 Oct 26;376(6):41. doi: 10.1007/s41061-018-0220-5.
3
Recent Advances in Bimetallic Cu-Based Nanocrystals for Electrocatalytic CO Conversion.用于电催化CO转化的双金属铜基纳米晶体的最新进展
Chem Asian J. 2021 Aug 16;16(16):2168-2184. doi: 10.1002/asia.202100583. Epub 2021 Jul 9.
4
Tracking heterogeneous structural motifs and the redox behaviour of copper-zinc nanocatalysts for the electrocatalytic CO reduction using operando time resolved spectroscopy and machine learning.使用原位时间分辨光谱和机器学习追踪铜锌纳米催化剂用于电催化CO还原的异质结构基序和氧化还原行为。
Catal Sci Technol. 2022 Mar 10;12(9):3028-3043. doi: 10.1039/d2cy00227b. eCollection 2022 May 10.
5
Polymer-Covered Copper Catalysts Alter the Reaction Pathway of the Electrochemical CO Reduction Reaction.聚合物包覆的铜催化剂改变了电化学CO还原反应的反应路径。
ACS Omega. 2022 Nov 14;7(47):42655-42663. doi: 10.1021/acsomega.2c05920. eCollection 2022 Nov 29.
6
Copper-based catalysts for the electrochemical reduction of carbon dioxide: progress and future prospects.用于二氧化碳电化学还原的铜基催化剂：进展与展望。
Mater Horiz. 2023 Mar 6;10(3):698-721. doi: 10.1039/d2mh01218a.
7
CO Reduction: From the Electrochemical to Photochemical Approach.一氧化碳还原：从电化学方法到光化学方法。
Adv Sci (Weinh). 2017 Sep 12;4(11):1700194. doi: 10.1002/advs.201700194. eCollection 2017 Nov.
8
Recent Advances in Solar Thermal Electrochemical Process (STEP) for Carbon Neutral Products and High Value Nanocarbons.用于碳中和产品和高价值纳米碳的太阳能热电化学工艺（STEP）的最新进展
Acc Chem Res. 2019 Nov 19;52(11):3177-3187. doi: 10.1021/acs.accounts.9b00405. Epub 2019 Nov 7.
9
Engineering the atomic arrangement of bimetallic catalysts for electrochemical CO reduction.设计用于电化学CO还原的双金属催化剂的原子排列
Chem Commun (Camb). 2021 Feb 23;57(15):1839-1854. doi: 10.1039/d0cc07589b.
10
Anionic Coordination Control in Building Cu-Based Electrocatalytic Materials for CO Reduction Reaction.用于CO还原反应的铜基电催化材料构建中的阴离子配位控制
Small. 2024 Aug;20(34):e2400661. doi: 10.1002/smll.202400661. Epub 2024 Apr 10.

引用本文的文献

1
Unveiling Ag-Modulated Cu Active Sites for Enhanced Multicarbon Product Formation in CO Electroreduction.揭示银调制的铜活性位点以增强二氧化碳电还原中多碳产物的生成
J Phys Chem Lett. 2025 Sep 4;16(35):9088-9096. doi: 10.1021/acs.jpclett.5c01788. Epub 2025 Aug 26.
2
Cu-Based Materials for Enhanced C Product Selectivity in Photo-/Electro-Catalytic CO Reduction: Challenges and Prospects.用于光/电催化CO还原中提高C产物选择性的铜基材料：挑战与展望
Nanomicro Lett. 2024 Jan 4;16(1):64. doi: 10.1007/s40820-023-01276-2.

本文引用的文献

1
Electroreduction of carbon dioxide to multi-electron reduction products using poly(ionic liquid)-based Cu-Pd catalyst.使用基于聚离子液体的铜钯催化剂将二氧化碳电还原为多电子还原产物。
Fundam Res. 2022 Jan 1;2(6):937-945. doi: 10.1016/j.fmre.2021.12.009. eCollection 2022 Nov.
2
Synergy effects on Sn-Cu alloy catalyst for efficient CO electroreduction to formate with high mass activity.用于高效将CO电还原为甲酸盐且具有高质量活性的Sn-Cu合金催化剂的协同效应。
Sci Bull (Beijing). 2020 May 15;65(9):711-719. doi: 10.1016/j.scib.2020.01.020. Epub 2020 Jan 23.
3
Author Correction: Steering surface reconstruction of copper with electrolyte additives for CO electroreduction.
作者更正：用于CO电还原的含电解质添加剂的铜的表面重构
Nat Commun. 2022 Jul 13;13(1):4059. doi: 10.1038/s41467-022-31696-4.
4
Accelerating CO Electroreduction to Multicarbon Products via Synergistic Electric-Thermal Field on Copper Nanoneedles.通过铜纳米针上的协同电场-热场加速一氧化碳电还原为多碳产物
J Am Chem Soc. 2022 Feb 23;144(7):3039-3049. doi: 10.1021/jacs.1c11253. Epub 2022 Feb 3.
5
Guiding the Catalytic Properties of Copper for Electrochemical CO Reduction by Metal Atom Decoration.
ACS Appl Mater Interfaces. 2021 Nov 10;13(44):52044-52054. doi: 10.1021/acsami.1c09128. Epub 2021 Aug 20.
6
Ethylene Selectivity in Electrocatalytic CO Reduction on Cu Nanomaterials: A Crystal Phase-Dependent Study.铜纳米材料上电催化CO还原反应中的乙烯选择性：一项与晶相相关的研究
J Am Chem Soc. 2020 Jul 22;142(29):12760-12766. doi: 10.1021/jacs.0c04981. Epub 2020 Jul 7.
7
Atomic Layer Deposition of ZnO on CuO Enables Selective and Efficient Electroreduction of Carbon Dioxide to Liquid Fuels.在氧化铜上进行氧化锌的原子层沉积可实现二氧化碳选择性高效电还原为液体燃料。
Angew Chem Int Ed Engl. 2019 Oct 14;58(42):15036-15040. doi: 10.1002/anie.201909610. Epub 2019 Sep 10.
8
Progress and Perspectives of Electrochemical CO Reduction on Copper in Aqueous Electrolyte.电化学 CO 还原在水溶液电解质中铜上的进展与展望。
Chem Rev. 2019 Jun 26;119(12):7610-7672. doi: 10.1021/acs.chemrev.8b00705. Epub 2019 May 22.
9
Copper⁻Silver Bimetallic Nanowire Arrays for Electrochemical Reduction of Carbon Dioxide.用于二氧化碳电化学还原的铜银双金属纳米线阵列
Nanomaterials (Basel). 2019 Jan 30;9(2):173. doi: 10.3390/nano9020173.
10
Structural Sensitivities in Bimetallic Catalysts for Electrochemical CO Reduction Revealed by Ag-Cu Nanodimers.银-铜纳米二聚体揭示的用于电化学CO还原的双金属催化剂中的结构敏感性
J Am Chem Soc. 2019 Feb 13;141(6):2490-2499. doi: 10.1021/jacs.8b12381. Epub 2019 Feb 4.