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分析再生塑料改性沥青中可能存在的致癌化合物。

Analysis of possible carcinogenic compounds in recycled plastic modified asphalt.

机构信息

Civil and Infrastructure Engineering, Royal Melbourne Institute of Technology (RMIT) University, 124 La Trobe St, VIC, 3001 Melbourne, Australia.

Analytical Chemistry, Royal Melbourne Institute of Technology (RMIT) University, 124 La Trobe St, VIC, 3001 Melbourne, Australia.

出版信息

Sci Total Environ. 2023 Feb 1;858(Pt 2):159910. doi: 10.1016/j.scitotenv.2022.159910. Epub 2022 Nov 3.

Abstract

The incorporation of recycled plastics in asphalt mixtures is getting a growing interest, however, exposing recycled plastics to the high working temperatures of asphalt has posed health and safety concerns. Few studies have paid attention to assessing health and environmental risks concerning recycled plastic-modified asphalt. This study investigates the release of 6 carcinogenic compounds from asphalt modified with recycled plastics, 4 volatile organic compounds (VOCs) and 2 polycyclic aromatic hydrocarbons (PAHs). The concentration of each compound was quantified by GC-MS. Human health risk assessments were conducted using probabilistic methods to assess the risk for an average Australian construction worker to get non-carcinogenic and carcinogenic health issues when exposed to conventional and plastic-modified asphalt fumes. Results showed that non-carcinogenic and carcinogenic risks related to VOC carcinogens (benzene, trichloroethylene, tetrachloroethylene and styrene) are negligible while PAHs (benzo[a]pyrene and dibenz[a,h]anthracene) constitute a possible non-carcinogenic risk and low carcinogenic risk for workers exposed to asphalt fumes. Overall the incorporation of recycled plastic in asphalt reduced the risk for workers to get non-carcinogenic and carcinogenic health issues compared to conventional asphalt mixes. ENVIRONMENTAL IMPLICATION: With increasing trends of using recycled plastics as road materials, concerns about the exposure of workers to carcinogenic gaseous emissions have been raised. This study demonstrates a non-carcinogenic and carcinogenic risk assessment on exposure to recycled plastic modified asphalt fumes. The findings suggest that recycled plastics decrease non-carcinogenic and carcinogenic risks compared to conventional asphalt.

摘要

将回收塑料纳入沥青混合物的研究越来越受到关注,然而,将回收塑料暴露在沥青的高温工作环境下会引发健康和安全问题。很少有研究关注评估与回收塑料改性沥青相关的健康和环境风险。本研究调查了从回收塑料改性沥青中释放的 6 种致癌化合物、4 种挥发性有机化合物(VOCs)和 2 种多环芳烃(PAHs)。每种化合物的浓度均通过气相色谱-质谱联用仪进行定量。采用概率方法进行了人体健康风险评估,以评估普通澳大利亚建筑工人在接触传统沥青和塑料改性沥青烟雾时出现非致癌和致癌健康问题的风险。结果表明,与 VOC 致癌物质(苯、三氯乙烯、四氯乙烯和苯乙烯)相关的非致癌和致癌风险可以忽略不计,而 PAHs(苯并[a]芘和二苯并[a,h]蒽)构成了接触沥青烟雾的工人可能存在的非致癌风险和低致癌风险。总体而言,与传统沥青混合物相比,将回收塑料纳入沥青可降低工人出现非致癌和致癌健康问题的风险。环境影响:随着将回收塑料作为道路材料的趋势不断增加,人们对工人接触致癌气态排放物的担忧也随之增加。本研究对接触回收塑料改性沥青烟雾进行了非致癌和致癌风险评估。研究结果表明,与传统沥青相比,回收塑料降低了非致癌和致癌风险。

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