α-L-山梨醇苷乙酯
Ethyl α-l-sorboside.
作者信息
Nagayama Natsumi, Taniguchi Norito, Matsumoto Mao, Takeshita Kei, Ishii Tomohiko
机构信息
Department of Advanced Materials Science, Faculty of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, Japan.
Fushimi Pharmaceutical Co Ltd, 307 Minatomachi, Marugame, Kagawa 763-8605, Japan.
出版信息
IUCrdata. 2020 Dec 18;5(Pt 12):x201625. doi: 10.1107/S2414314620016259. eCollection 2020 Dec.
Ethyl l-sorboside, CHO, was prepared from the rare sugar l-sorbose, CHO, and crystallized. It was confirmed that ethyl l-sorboside formed α-pyran-ose with a conformation. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, forming a three-dimensional network. The unit-cell volume of the title ethyl α-l-sorboside is 940.63 Å ( = 4), which is about 194.69 Å (26.1%) bigger than that of l-sorbose [745.94 Å ( = 4)].
L-山梨醇乙酯（CHO）由稀有糖L-山梨糖（CHO）制备并结晶。已证实L-山梨醇乙酯形成具有一种构象的α-吡喃糖。在晶体中，分子通过O-H⋯O氢键相连，形成三维网络。标题化合物α-L-山梨醇乙酯的晶胞体积为940.63 ų（Z = 4），比L-山梨糖的晶胞体积[745.94 ų（Z = 4）]大约大194.69 ų（26.1%）。
Zotero 插件