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四氟硼酸硝鎓,NOBF₄ 。 (你原文中化学式有误,正确的应该是NOBF₄ )

Nitro-sonium tetra-fluorido-borate, NOBF.

作者信息

Lozinšek Matic

机构信息

Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia.

出版信息

IUCrdata. 2021 Nov 18;6(Pt 11):x211215. doi: 10.1107/S2414314621012153. eCollection 2021 Nov.

DOI:10.1107/S2414314621012153
PMID:36337464
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462292/
Abstract

The crystal structure of oxido-nitro-gen(1+) tetra-fluorido-borate (nitro-sonium tetra-fluorido-borate), NOBF , was refined on the basis of single-crystal X-ray diffraction data at 150 K. The compound crystallizes in the baryte structure type with ortho-rhom-bic symmetry. The crystal structure exhibits cationic disorder with equal occupation of N and O atoms at the same site.

摘要

氧化氮(1+)四氟硼酸盐(硝鎓四氟硼酸盐)NOBF₄的晶体结构基于150 K下的单晶X射线衍射数据进行了精修。该化合物以重晶石结构类型结晶,具有正交对称。晶体结构表现出阳离子无序,N和O原子在同一位置的占有率相等。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0c0/9462292/4138ea86ccb5/x-06-x211215-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0c0/9462292/f1708c5576d1/x-06-x211215-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0c0/9462292/4138ea86ccb5/x-06-x211215-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0c0/9462292/f1708c5576d1/x-06-x211215-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0c0/9462292/4138ea86ccb5/x-06-x211215-fig2.jpg

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Chemistry. 2016 Aug 16;22(34):12145-53. doi: 10.1002/chem.201602265. Epub 2016 Jul 14.
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Inorg Chem. 2005 Mar 7;44(5):1525-9. doi: 10.1021/ic048684p.