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4-（2,3-二氯苯基）哌嗪-1-鎓苦味酸盐

4-(2,3-Di-chloro-phen-yl)piperazin-1-ium picrate.

作者信息

Sathya Udhayasuriyan, Nirmal Ram Jeyaraman Selvaraj, Gomathi Sundaramoorthy, Ramu Shyamaladevi, Jegan Jennifer Samson, Ibrahim Abdul Razak

机构信息

Centre for Research and Development, PRIST Deemed to be University, Thanjavur, 613 403, Tamil Nadu, India.

Department of Chemistry, Periyar Maniammai Institute of Science and Technology, Thanjavur 613 403, Tamil Nadu, India.

出版信息

IUCrdata. 2021 Apr 13;6(Pt 4):x210379. doi: 10.1107/S2414314621003795. eCollection 2021 Apr.

DOI:10.1107/S2414314621003795
PMID:36339106
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462331/
Abstract

The title compound, CHNO ·CHClN , crystallizes with one 1-(2,3-di-chloro-phen-yl)piperazine (DP) cation and one picrate (PA) anion in the asymmetric unit. In the crystal structure, the DP cation and PA anion are inter-connected several N-H⋯O and C-H⋯O hydrogen bonds. The DP cation and PA anion are further connected through C-Cl⋯π [3.8201 (4), 3.7785 (4) Å] and N-O⋯π [3.7814 (4) Å] inter-actions. The DP cations are further inter-connected a weak inter-molecular Cl⋯Cl [3.2613 (4) Å] halogen-halogen inter-action. The combination of these supra-molecular inter-actions leads to a herringbone like supra-molecular architecture.

摘要

标题化合物CHNO·CHClN在不对称单元中结晶，含有一个1-(2,3-二氯苯基)哌嗪(DP)阳离子和一个苦味酸盐(PA)阴离子。在晶体结构中，DP阳离子和PA阴离子通过几个N-H⋯O和C-H⋯O氢键相互连接。DP阳离子和PA阴离子还通过C-Cl⋯π [3.8201 (4), 3.7785 (4) Å]和N-O⋯π [3.7814 (4) Å]相互作用进一步连接。DP阳离子通过弱分子间Cl⋯Cl [3.2613 (4) Å]卤-卤相互作用进一步相互连接。这些超分子相互作用的组合导致了类似人字形的超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/3dabb0eb6f65/x-06-x210379-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/c955f8a16748/x-06-x210379-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/94dca0b11e51/x-06-x210379-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/6e1654661cfe/x-06-x210379-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/9de8cc31e261/x-06-x210379-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/3dabb0eb6f65/x-06-x210379-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/c955f8a16748/x-06-x210379-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/94dca0b11e51/x-06-x210379-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/6e1654661cfe/x-06-x210379-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/9de8cc31e261/x-06-x210379-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a665/9462331/3dabb0eb6f65/x-06-x210379-fig5.jpg

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