双[μ-2-(吡啶-3-基)乙酸根-κ::']双-[μ-2-(吡啶-3-基)乙酸根-κ:']双-[氯-(1,10-菲咯啉-κ,')镝(III)]
Bis[μ-2-(pyridin-3-yl)acetato-κ ::']bis-[μ-2-(pyridin-3-yl)acetato-κ :']bis-[chlorido-(1,10-phenanthroline-κ ,')dysprosium(III)].
作者信息
Lin Yan, Yu Jian-Ping
机构信息
College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, 341000, People's Republic of China.
出版信息
IUCrdata. 2022 Mar 31;7(Pt 3):x220231. doi: 10.1107/S2414314622002310. eCollection 2022 Mar.
The title Dy complex, [Dy(CHNO)Cl(CHN)] or [Dy( -PAA)(Cl)(phen)] (PAA = 3-pyridyl-acetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO), 3-pyridyl-acetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Adjacent binuclear dimers are further connected face-to-face - stacking inter-actions resulting in supra-molecular chains along the -axis direction.
通过高氯酸镝、3 - 吡啶基乙酸配体和1,10 - 菲咯啉反应得到的标题配合物Dy络合物，即[Dy(CHNO)Cl(CHN)]或[Dy( - PAA)(Cl)(phen)]（PAA = 3 - 吡啶基乙酸酯，phen = 1,10 - 菲咯啉），呈现出双核结构。相邻的双核二聚体通过面对面的堆积相互作用进一步连接，从而沿轴方向形成超分子链。
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