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沥青质中氮、氧杂原子对氧钒/镍初卟啉吸附的影响

Impact of N, O Heteroatoms in Asphaltene on Adsorption of Vanadyl/Nickel Etioporphyrin.

作者信息

Chen Feifei, Wang Qin, Zhang Linzhou, Zhu Qiushi

机构信息

Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, Huaibei Normal University, Huaibei, Anhui235000, P. R. China.

State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing102249, China.

出版信息

ACS Omega. 2022 Oct 19;7(43):39078-39089. doi: 10.1021/acsomega.2c04811. eCollection 2022 Nov 1.

DOI:10.1021/acsomega.2c04811
PMID:36340180
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9631875/
Abstract

The interaction between functionalized graphene and metal porphyrins was studied for a better understanding of the influence of the N and O heteroatoms in asphaltene on demetallization efficiency during the solvent deasphalting process. The theoretical simulation indicated a strong inhibitory effect of the aminated/carboxylated side group for chemical adsorption of metal porphyrins. The differences of adsorption behavior for graphene, aminated graphene, and Canadian oil sands bitumen vacuum tower bottom asphaltene (VTB-asp) were also analyzed. It was found that the introduction of aminated side groups to the graphene not only compromised the electron delocalization capacity of the polyaromatic nuclei hydrocarbon skeleton of graphene but also caused a steric hindrance effect on the internal diffusion of metal porphyrins, leading to decreased adsorption active sites and internal diffusion rate, respectively. It was also found that metal porphyrins can be barely adsorbed on carboxylated graphene at 25 °C.

摘要

为了更好地理解溶剂脱沥青过程中沥青质中氮和氧杂原子对脱金属效率的影响，研究了功能化石墨烯与金属卟啉之间的相互作用。理论模拟表明，胺化/羧化侧基对金属卟啉的化学吸附具有强烈的抑制作用。还分析了石墨烯、胺化石墨烯和加拿大油砂沥青真空塔底油沥青质（VTB-asp）吸附行为的差异。研究发现，在石墨烯中引入胺化侧基不仅损害了石墨烯多环核烃骨架的电子离域能力，而且对金属卟啉的内部扩散产生空间位阻效应，分别导致吸附活性位点和内部扩散速率降低。还发现，在25℃下，金属卟啉几乎不能吸附在羧化石墨烯上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/31e9dede2ab4/ao2c04811_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/7017d2d8fe79/ao2c04811_0002.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/add24991a20c/ao2c04811_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/3c01d8b0642c/ao2c04811_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/016609aab004/ao2c04811_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/29caf945c0de/ao2c04811_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/57c5a531dc13/ao2c04811_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/31e9dede2ab4/ao2c04811_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/7017d2d8fe79/ao2c04811_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/cc2b32c72073/ao2c04811_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/0d41e79da2f0/ao2c04811_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/add24991a20c/ao2c04811_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/3c01d8b0642c/ao2c04811_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/016609aab004/ao2c04811_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/29caf945c0de/ao2c04811_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/57c5a531dc13/ao2c04811_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3611/9631875/31e9dede2ab4/ao2c04811_0010.jpg

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本文引用的文献

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J Hazard Mater. 2019 Dec 15;380:120789. doi: 10.1016/j.jhazmat.2019.120789. Epub 2019 Jun 28.
2
Microcalorimetry Study of the Adsorption of Asphaltenes and Asphaltene Model Compounds at the Liquid-Solid Surface.微量热法研究沥青质及沥青质模型化合物在固-液界面的吸附
Langmuir. 2016 Jul 26;32(29):7294-305. doi: 10.1021/acs.langmuir.6b00816. Epub 2016 Jul 11.
3
Design of a new integrated chitosan-PAMAM dendrimer biosorbent for heavy metals removing and study of its adsorption kinetics and thermodynamics.
设计一种新型的壳聚糖-PAMAM 树枝状大分子生物吸附剂用于去除重金属，并研究其吸附动力学和热力学。
Bioresour Technol. 2016 Apr;205:230-8. doi: 10.1016/j.biortech.2016.01.052. Epub 2016 Jan 23.
4
Unraveling the Molecular Structures of Asphaltenes by Atomic Force Microscopy.利用原子力显微镜解析沥青质的分子结构。
J Am Chem Soc. 2015 Aug 12;137(31):9870-6. doi: 10.1021/jacs.5b04056. Epub 2015 Jul 30.
5
New vanadium compounds in Venezuela heavy crude oil detected by positive-ion electrospray ionization fourier transform ion cyclotron resonance mass spectrometry.通过正离子电喷雾电离傅里叶变换离子回旋共振质谱法检测委内瑞拉重质原油中的新型钒化合物。
Sci Rep. 2014 Jun 20;4:5373. doi: 10.1038/srep05373.
6
Adsorption of asphaltenes from heavy oil onto in situ prepared NiO nanoparticles.重油中沥青质在原位制备的NiO纳米颗粒上的吸附
J Colloid Interface Sci. 2012 Jul 15;378(1):64-9. doi: 10.1016/j.jcis.2012.04.016. Epub 2012 Apr 19.
7
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Rapid Commun Mass Spectrom. 2008 Jul;22(14):2153-60. doi: 10.1002/rcm.3600.