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二-μ-氯代-双-{氯代-[2,4,6-三-(吡啶-2-基)-1,3,5-三嗪-κ³N¹,N³,N⁵]镍(II)}

Di-μ-chlorido-bis-{chlorido-[2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine-κ , , ]nickel(II)}.

作者信息

Ha Kwang

机构信息

Chonnam National University, School of Chemical Engineering, Research Institute of Catalysis, Gwangju, Republic of Korea.

出版信息

IUCrdata. 2021 Jan 29;6(Pt 1):x210093. doi: 10.1107/S2414314621000936. eCollection 2021 Jan.

DOI:10.1107/S2414314621000936
PMID:36340472
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462264/
Abstract

In the title compound, [NiCl(CHN)], the Ni ions are hexa-coordinated in a distorted octa-hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl anions in a meridional geometry. The two Ni ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the NiCl ring.

摘要

在标题化合物[NiCl(CHN)]中，Ni离子在一个扭曲的八面体配位环境中六配位，该环境由三齿的2,4,6-三(2-吡啶基)-1,3,5-三嗪配体的三个N原子和三个Cl阴离子以经式几何构型定义。两个Ni离子由两个Cl阴离子配体桥连，从而形成一个双核配合物。一个晶体学反演中心位于NiCl环的质心处。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cca1/9462264/2f8e26869e13/x-06-x210093-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cca1/9462264/b52237d79370/x-06-x210093-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cca1/9462264/2f8e26869e13/x-06-x210093-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cca1/9462264/b52237d79370/x-06-x210093-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cca1/9462264/2f8e26869e13/x-06-x210093-fig2.jpg

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