双[3,5-二氟-2-(吡啶-2-基)苯基](4,4'-二甲氧基-2,2'-联吡啶)铱(III)六氟磷酸酯
Bis[3,5-di-fluoro-2-(pyridin-2-yl)phen-yl](4,4'-di-meth-oxy-2,2'-bi-pyridine)-iridium(III) hexa-fluorido-phosphate.
作者信息
Shevlin Madelyn R, Stumbo Emily E, McMillen Colin D, Pienkos Jared A
机构信息
Department of Chemistry and Physics, University of Tennessee at Chattanooga, Chattanooga, TN 37403, USA.
Department of Chemistry, Clemson University, Clemson, SC 29634, USA.
出版信息
IUCrdata. 2022 Aug 26;7(Pt 8):x220830. doi: 10.1107/S2414314622008306. eCollection 2022 Aug.
The title cyclo-metalated distorted octa-hedral iridium complex, [Ir(CHFN)(CHNO)]PF, exhibits elongated Ir-N bonds to the dimeth-oxy bi-pyridine ligand [2.128 (3) and 2.136 (3) Å] where these nitro-gen atoms are to the Ir-C bonds of the two cyclo-metalating di-fluoro-phenyl-pyridine ligands. The angles between the mean planes of the phenyl and pyridyl fragments within the individual ligands range from 3.5 (2) to 11.4 (2)° to deviate slightly from coplanarity.
标题为环金属化扭曲八面体铱配合物[Ir(CHFN)(CHNO)]PF，其二甲氧基联吡啶配体的Ir-N键伸长[2.128 (3) 和2.136 (3) Å]，其中这些氮原子与两个环金属化二氟苯基吡啶配体的Ir-C键相连。单个配体内苯基和吡啶基片段平均平面之间的夹角范围为3.5 (2) 至11.4 (2)°，略微偏离共面性。
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