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使用海藻酸钠-明胶-蒙脱石三元复合微球吸附去除废水中的结晶紫。

Adsorptive removal of crystal violet from wastewater using sodium alginate-gelatin-montmorillonite ternary composite microbeads.

作者信息

Akin Kubra, Ugraskan Volkan, Isik Birol, Cakar Fatih

机构信息

Department of Chemistry, Faculty of Arts & Sciences, Yildiz Technical University, Esenler, Istanbul 34220, Turkey.

Department of Chemistry, Faculty of Arts & Sciences, Yildiz Technical University, Esenler, Istanbul 34220, Turkey.

出版信息

Int J Biol Macromol. 2022 Dec 31;223(Pt A):543-554. doi: 10.1016/j.ijbiomac.2022.11.002. Epub 2022 Nov 5.

Abstract

In this study, the performance of the montmorillonite-filled sodium alginate/gelatin (SA-GEL-MMT) ternary biocomposite microbeads on the adsorptive removal of crystal violet (CV) dye was investigated. Firstly, the composites containing different weight ratios of MMT such as 10 %, 15 %, and 20 % were prepared. The composite beads were cross-linked using a calcium chloride (3%wt/v) solution. To determine the optimum sorption conditions the studies were performed at different parameters namely temperature, pH, contact time, sorbent dose, and dye concentration. From the sorption studies, the maximum capacity of the microbeads was found as 1000.0 mg/g whereas the maximum removal of the dye was 92.1 % at pH = 7 and a temperature of 25 °C. Additionally, the kinetic studies showed that the sorption of the dye followed the pseudo-second-order kinetics. Moreover, the adsorptive removal of the dye occurs spontaneously. This study suggests that the use of SA-GEL-MMT can be highly effective and reusable for the treatment of wastewater.

摘要

在本研究中,对蒙脱石填充的海藻酸钠/明胶(SA-GEL-MMT)三元生物复合微球吸附去除结晶紫(CV)染料的性能进行了研究。首先,制备了含有10%、15%和20%等不同重量比蒙脱石的复合材料。复合微球用氯化钙(3%wt/v)溶液交联。为了确定最佳吸附条件,在不同参数下进行了研究,即温度、pH值、接触时间、吸附剂剂量和染料浓度。从吸附研究中发现,微球的最大吸附容量为1000.0 mg/g,而在pH = 7和温度为25°C时,染料的最大去除率为92.1%。此外,动力学研究表明,染料的吸附遵循准二级动力学。而且,染料的吸附去除是自发进行的。本研究表明,SA-GEL-MMT用于废水处理具有高效性和可重复使用性。

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