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基于 GO/PPy 修饰玻碳电极的 SnOQDs 用于高效电化学过氧化氢传感器。

SnOQDs Deposited on GO/PPy-Modified Glassy Carbon Electrode for Efficient Electrochemical Hydrogen Peroxide Sensor.

机构信息

Department of Chemistry, CHRIST (Deemed to be University), Bangalore 560029, India.

Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Bangalore 560029, India.

出版信息

Biosensors (Basel). 2022 Nov 7;12(11):983. doi: 10.3390/bios12110983.

DOI:10.3390/bios12110983
PMID:36354492
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9688144/
Abstract

In this present work, we demonstrate an efficient electrochemical sensor for the detection of hydrogen peroxide (HO) using a glassy carbon electrode (GCE) modified with a ternary nanocomposite of tin oxide QDs/GO/PPy (SGP2). An in situ chemical oxidative polymerization method was used to create the SGP2 nanocomposite. FTIR, XRD, HR TEM, CV, DPV, and impedance analysis were used to characterize the nanocomposite. The SGP2 nanocomposite modified GCE can be used to create an effective HO electrochemical sensor with high sensitivity and a low detection limit (LOD). With SGP2 modified GCE, the electrochemical detection test for HO was carried out using cyclic voltammetry (CV) and amperometric methods. The SGP2 modified GCE shows improved sensing capabilities, resulting in considerable sensitivity of 11.69 µA mM cm and a very low limit of detection (LOD) of 0.758 µM for a broad linear range of HO concentration from 0.1 mM to 0.8 mM with a correlation coefficient R = 0.9886. Additionally, the performance of the SGP2-modified GCE electrode is on par with or nonetheless superior to that of the other functional materials that have been reported for HO. As a result, our findings suggest that combining conductive polymer with metal oxide may be a useful method for producing sophisticated and affordable electrochemical sensors.

摘要

在本工作中,我们展示了一种使用玻璃碳电极(GCE)修饰的三元纳米复合材料氧化锡量子点/GO/PPy(SGP2)来检测过氧化氢(HO)的高效电化学传感器。采用原位化学氧化聚合方法制备了 SGP2 纳米复合材料。使用傅里叶变换红外光谱(FTIR)、X 射线衍射(XRD)、高分辨率透射电子显微镜(HR-TEM)、循环伏安法(CV)、差分脉冲伏安法(DPV)和阻抗分析对纳米复合材料进行了表征。SGP2 纳米复合材料修饰的 GCE 可用于构建具有高灵敏度和低检测限(LOD)的有效 HO 电化学传感器。使用 SGP2 修饰的 GCE,通过循环伏安法(CV)和安培法进行了 HO 的电化学检测试验。SGP2 修饰的 GCE 显示出改进的传感性能,导致对 HO 的浓度在 0.1 mM 至 0.8 mM 之间的宽线性范围内具有相当大的灵敏度(11.69 µA mM cm)和非常低的检测限(LOD)(0.758 µM),相关系数 R = 0.9886。此外,SGP2 修饰的 GCE 电极的性能与已经报道的用于 HO 的其他功能材料相当或甚至更优。因此,我们的研究结果表明,将导电聚合物与金属氧化物结合可能是制造复杂且经济实惠的电化学传感器的一种有效方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c5d0/9688144/9cc0129a7ec2/biosensors-12-00983-g014.jpg
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