Hala Miroslav, Mališ Jakub, Paidar Martin, Bouzek Karel
Department of Inorganic Technology, University of Chemistry and Technology, Prague, Technická 5, 16628 Prague, Czech Republic.
Membranes (Basel). 2022 Oct 27;12(11):1050. doi: 10.3390/membranes12111050.
Bipolar plates represent a crucial component of the PEM fuel cell stack. Polymer-carbon composites are recognized as state-of-the-art materials for bipolar plate manufacturing, but their use involves a compromise between electrical and heat conductivity, mechanical strength and costs. Thus, all key parameters must be considered when selecting a suitable plate satisfying the demands of the desired application. However, data relevant to commercial materials for such selection are scarce in the open literature. To address this issue, 13 commercially available polymer-carbon composites are characterised in terms of the following parameters: through-plane conductivity, hydrogen permeability, mechanical strength, water uptake, density, water contact angle and chemical stability. None of the materials tested reached the DOE target for electrical conductivity, while five of the materials met the target for flexural strength. The overall best-performing material showed a conductivity value of 50.4 S·cm and flexural strength of 40.1 MPa. The data collected provide important supporting information in selecting the materials most suitable for the desired application. In addition, the key parameters determined for each bipolar plate supply important input parameters for the mathematical modelling of fuel cells.
双极板是质子交换膜燃料电池堆的关键部件。聚合物-碳复合材料被认为是双极板制造的先进材料,但其使用涉及到电导率和热导率、机械强度和成本之间的权衡。因此,在选择满足所需应用需求的合适板材时,必须考虑所有关键参数。然而,公开文献中缺乏与用于此类选择的商业材料相关的数据。为了解决这个问题,对13种市售的聚合物-碳复合材料进行了以下参数的表征:面内电导率、氢渗透率、机械强度、吸水率、密度、水接触角和化学稳定性。测试的材料均未达到美国能源部的电导率目标,而其中五种材料达到了抗弯强度目标。总体表现最佳的材料的电导率值为50.4 S·cm,抗弯强度为40.1 MPa。收集到的数据为选择最适合所需应用的材料提供了重要的支持信息。此外,为每个双极板确定的关键参数为燃料电池的数学建模提供了重要的输入参数。