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内边缘取代[5]螺旋芴衍生膦的氧化同步增强圆偏振发光。

Oxidation of an Internal-Edge-Substituted [5]Helicene-Derived Phosphine Synchronously Enhances Circularly Polarized Luminescence.

机构信息

Faculty of Pharmaceutical Sciences, Showa Pharmaceutical University, Higashi-Tamagawagakuen, Machida, Tokyo, 194-8543, Japan.

Graduate School of Pharmaceutical Sciences, Kyushu University, Maidashi Higashi-ku, Fukuoka, 812-8582, Japan.

出版信息

Chemistry. 2022 Nov 21;28(65):e202203413. doi: 10.1002/chem.202203413. Epub 2022 Nov 11.

Abstract

Invited for the cover of this issue are the groups of Kazuteru Usui and Satoru Karasawa at Showa Pharmaceutical University, and Yoshitane Imai at Kindai University. The image depicts how a phosphine-oxide-bearing helicene exhibits markedly enhanced CPL response in the excited state compared with that of one with a corresponding phosphine. Read the full text of the article at 10.1002/chem.202202922.

摘要

本期特邀嘉宾是昭和药科大学的内藤和也(Kazuteru Usui)和狩野哲郎(Satoru Karasawa)小组,以及近畿大学的今井嘉彦(Yoshitane Imai)。该图像描绘了含氧化膦的螺旋烯在激发态下与相应的膦相比,表现出明显增强的 CPL 响应。阅读全文请点击 10.1002/chem.202202922。

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