锂离子导电非晶态氮氧化锂磷的电子性质
Electronic properties of lithium-ion conductive amorphous lithium phosphorus oxynitride.
作者信息
Nakayama Futa, Suzuki Yasuhiro, Yoshikawa Keisuke, Yamamoto Satoshi, Sakakura Miyuki, Ohnishi Tsuyoshi, Iriyama Yasutoshi
机构信息
Department of Materials Design Engineering, Graduate School of engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, 4648606, Japan.
Center for Green Research on Energy and Environmental Materials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 3050044, Japan.
出版信息
Chem Commun (Camb). 2022 Nov 29;58(95):13262-13265. doi: 10.1039/d2cc05117f.
The valence band maxima of Li conductive amorphous lithium phosphorus oxynitride (LiPON) electrolyte depend on the chemical bonding states, and isolated nonbonding oxygen raises them. In contrast, the conduction band minima of the LiPON are independent of the composition and the values are less than the work function of Li.
锂导电非晶态氮氧化磷锂（LiPON）电解质的价带最大值取决于化学键合状态，孤立的非键合氧会使其升高。相比之下，LiPON的导带最小值与组成无关，其值小于锂的功函数。
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