Ball milling and acetic acid co-modified sludge biochar enhanced by electrochemistry to activate peroxymonosulfate for sustainable degradation of environmental concentration neonicotinoids.

Neonicotinoids pose potential serious risks to human health even at environmental concentration and their removal from water is considered as a great challenge. A novel ball milling and acetic acid co-modified sludge biochar (BASBC) was the first time synthesized, which performed superior physicochemical characteristics including larger surface area, more defect structures and functional groups (e.g., CO and -OH). Electrochemistry was introduced to enhance BASBC for peroxymonosulfate (PMS) activation (E/BASBC/PMS) to degrade environmental concentration neonicotinoids (e.g., imidacloprid (IMI)). The degradation efficiency of IMI was 95.2% within 60 min (C (PMS)= 1 mM, E= 25 V, m (BASBC)= 10 mg). Solution pH and anionic species/concentrations were critical affecting factors. The scavenging and electron paramagnetic resonance experiments suggested that OH and O were the dominant reactive oxygen species contributing to IMI degradation. Three degradation pathways were proposed and pathway Ⅲ was the main one. 86.1% of IMI were mineralized into non-toxic CO and HO, and others were converted into less toxic intermediates. Also, E/BASBC/PMS system achieved the sustainable degradation of IMI in the cycle experiments. Additionally, it exhibited excellent degradation performance for other three typical neonicotinoids (96.6% of thiacloprid (THI), 96.5% of thiamethoxam (THX) and 82.6% of clothianidin (CLO)) with high mineralization efficiencies (87.8% of THI, 90.5% of THX and 75.4% of CLO).