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变废为宝:聚吡咯沉积于废旧口罩用于去除六价铬及脱盐

Turning waste into valuables: deposition of polypyrrole on the obsolete mask for Cr(VI) removal and desalination.

作者信息

Zhou Fengkai, Li Yimeng, Wang Shasha, Wu Xinkang, Peng Jiamin, Wang Fujun, Wang Lu, Mao Jifu

机构信息

Key Laboratory of Textile Science & Technology, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China.

Key Laboratory of Textile Industry for Biomedical Textile Materials and Technology, Donghua University, Shanghai 201620, China.

出版信息

Sep Purif Technol. 2023 Feb 15;306:122643. doi: 10.1016/j.seppur.2022.122643. Epub 2022 Nov 14.

Abstract

The global mask consumption has been exacerbated because of the coronavirus disease 2019 (COVID-19) pandemic. Simultaneously, the traditional mask disposal methods (incineration and landfill) have caused serious environmental pollution and waste of resources. Herein, a simple and green mass-production method has been proposed to recycle carbon protective mask (CPM) into the carbon protective mask/polydopamine/polypyrrole (CPM/PDA/PPy) composite by polymerization of PPy. The CPM/PDA/PPy composite was used for the removal of Cr(VI) and salt ions to produce clean water. The synergistic effect of PPy and the CPM improved the removal capability of Cr(VI). The CPM/PDA/PPy composite provided high adsorption capacity (358.68 mg g) and economic value (811.42 mg $). Consequently, the CPM/PDA/PPy (cathode) was combined with MnO (anode) for desalination in CDI cells, demonstrated excellent desalination capacity (26.65 mg g) and ultrafast salt adsorption rate (6.96 mg g min), which was higher than conventional CDI cells. Our work proposes a new low-carbon strategy to recycle discarded masks and demonstrates their utilization in Cr(VI) removal and seawater desalination.

摘要

由于2019冠状病毒病(COVID-19)大流行,全球口罩消费量激增。与此同时,传统的口罩处理方法(焚烧和填埋)造成了严重的环境污染和资源浪费。在此,我们提出了一种简单且绿色的大规模生产方法,通过聚吡咯(PPy)聚合将碳防护口罩(CPM)回收制成碳防护口罩/聚多巴胺/聚吡咯(CPM/PDA/PPy)复合材料。CPM/PDA/PPy复合材料用于去除六价铬(Cr(VI))和盐离子以生产清洁水。PPy与CPM的协同效应提高了对Cr(VI)的去除能力。CPM/PDA/PPy复合材料具有高吸附容量(358.68 mg g)和经济价值(811.42 mg $)。因此,CPM/PDA/PPy(阴极)与MnO(阳极)结合用于电容去离子(CDI)电池中的脱盐,表现出优异的脱盐容量(26.65 mg g)和超快的盐吸附速率(6.96 mg g min),高于传统的CDI电池。我们的工作提出了一种回收废弃口罩的新型低碳策略,并展示了其在去除Cr(VI)和海水淡化方面的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0c7/9661547/fb41aa75dcc1/ga1_lrg.jpg

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