Manganese-Catalyzed Chemoselective Hydrosilylation of Nitroarenes: Sustainable Route to Aromatic Amines.

Herein we report efficient catalytic hydrosilylations of nitroarenes to form the corresponding aromatic amines using a well-defined manganese(II)-NNO pincer complex with a low catalyst loading (1 mol %) under solvent-free conditions. This base-metal-catalyzed hydrosilylation is an easy and sustainable alternative to classical hydrogenation. A large variety of nitroarenes bearing various functionalities were selectively transformed into the corresponding aromatic amines in good yields. The potential utility of the present catalytic protocol was demonstrated by the preparation of commercial drug molecules.