Panda Surajit, Nanda Amareshwar, Behera Rakesh R, Ghosh Rahul, Bagh Bidraha
School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute, Bhubaneswar, Jatni, Khurda, Odisha, PIN 752050, India.
Chem Commun (Camb). 2023 Apr 11;59(30):4527-4530. doi: 10.1039/d3cc00328k.
Commercially available Co(CO) was used as an effective catalyst for the hydrosilylation of nitroarenes under both thermal and photochemical conditions. A wide variety of nitroarenes with various functionalities were selectively reduced to aromatic amines. Syntheses of drug molecules expand the potential utility of this protocol. Experimental evidence suggested a radical pathway.
市售的Co(CO)在热化学和光化学条件下均用作硝基芳烃硅氢化反应的有效催化剂。多种具有不同官能团的硝基芳烃被选择性还原为芳香胺。药物分子的合成拓展了该方法的潜在应用。实验证据表明存在自由基途径。
