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切向驱动的活性极性线性聚合物——一项分析研究。

Tangentially driven active polar linear polymers-An analytical study.

作者信息

Philipps Christian A, Gompper Gerhard, Winkler Roland G

机构信息

Theoretical Physics of Living Matter, Institute of Biological Information Processing and Institute for Advanced Simulation, Forschungszentrum Jülich and JARA, D-52425 Jülich, Germany.

出版信息

J Chem Phys. 2022 Nov 21;157(19):194904. doi: 10.1063/5.0120493.

Abstract

The conformational and dynamical properties of isolated flexible active polar linear polymers (APLPs) are studied analytically. The APLPs are modeled as Gaussian bead-spring linear chains augmented by tangential active forces, both in a discrete and continuous representation. The polar forces lead to linear non-Hermitian equations of motion, which are solved by an eigenfunction expansion in terms of a biorthogonal basis set. Our calculations show that the polymer conformations are independent of activity. However, tangential propulsion strongly impacts the polymer dynamics and yields an active ballistic regime as well as an activity-enhanced long-time diffusive regime, which are both absent in passive systems. The polar forces imply a coupling of modes in the eigenfunction representation, in particular with the translational mode, with a respective strong influence on the polymer dynamics. The total polymer mean-square displacement on scales smaller than the radius of gyration is determined by the active internal dynamics rather than the collective center-of-mass motion, in contrast to active Brownian polymers at large Péclet numbers, reflecting the distinct difference in the propulsion mechanism.

摘要

对孤立的柔性活性极性线性聚合物(APLPs)的构象和动力学性质进行了分析研究。APLPs被建模为通过切向活性力增强的高斯珠-弹簧线性链,采用离散和连续两种表示形式。极性力导致线性非厄米运动方程,通过双正交基集的本征函数展开求解。我们的计算表明,聚合物构象与活性无关。然而,切向推进强烈影响聚合物动力学,并产生活性弹道 regime 以及活性增强的长时间扩散 regime,这两种情况在被动系统中均不存在。极性力意味着在本征函数表示中模式的耦合,特别是与平移模式的耦合,对聚合物动力学有相应的强烈影响。与大佩克莱数下的活性布朗聚合物相比,聚合物在小于回转半径尺度上的总均方位移由活性内部动力学而非集体质心运动决定,这反映了推进机制的明显差异。

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