Department of Engineering Physics, Air Force Institute of Technology, Wright-Patterson AFB, OH, USA.
Appl Spectrosc. 2023 Apr;77(4):335-349. doi: 10.1177/00037028221144642. Epub 2023 Feb 2.
A tunable diode laser absorption spectroscopy (TDLAS) device has been developed to study long-path atmospheric transmission near diode pumped alkali laser (DPAL) emission wavelengths. By employing a single aperture and retro reflector in a mono-static configuration, the noise associated with atmospheric and platform jitter were reduced by a factor of ∼30 and the open-air path length was extended to 4.4 km and over a very broad spectral range, up to 120 cm. Water vapor absorption lines near the rubidium (Rb) and cesium (Cs) variants of the DPAL near 795 and 894 nm, oxygen lines near the potassium (K) DPAL near 770 nm, and water vapor absorption in the vicinity of the neodymium-doped yttrium aluminum garnet (Nd:YAG) laser 1.064 μm and chemical oxygen iodine laser (COIL) 1.3 μm lines were studied. The detection limit for path absorbance increases from ΔA = 0.0017 at 100 m path length to 0.085 for the 4.4 km path. Comparison with meteorological instruments for maritime and desert environments yields agreement for the 2.032 km path to within 1.5% for temperature, 4.5% for pressure, and 5.1% for concentration, while agreements for the 4.4 km path are within 1.4% for temperature, 7.7% for pressure, and 23.5% for concentration. An intra cavity output spectroscopy (ICOS) device was also used as a spectral reference to verify location of atmospheric lines. Implications of TDLAS collection system design on signal-to-noise (S/N) are discussed as well as the effect of path turbulence on baseline noise and inform the selection of the DPAL variant least affected by molecular absorption.
已经开发出一种可调谐二极管激光吸收光谱(TDLAS)设备,用于研究近二极管泵浦碱激光(DPAL)发射波长的长路径大气传输。通过在单静态配置中使用单个孔径和后向反射器,与大气和平台抖动相关的噪声降低了约 30 倍,并且开放空气路径长度扩展到 4.4 公里以上,并且具有非常宽的光谱范围,高达 120 厘米。在 DPAL 的铷(Rb)和铯(Cs)变体附近的水汽吸收线在 795nm 和 894nm 附近,钾(K)DPAL 附近的氧气线在 770nm 附近,以及掺钕钇铝石榴石(Nd:YAG)激光附近的水汽吸收 1.064μm 和化学氧碘激光(COIL)1.3μm 线。路径吸收率的检测限从 100m 路径的ΔA=0.0017 增加到 4.4km 路径的 0.085。与海洋和沙漠环境的气象仪器进行比较,2.032km 路径的温度误差在 1.5%以内,压力误差在 4.5%以内,浓度误差在 5.1%以内,而 4.4km 路径的温度误差在 1.4%以内,压力误差在 7.7%以内,浓度误差在 23.5%以内。腔内输出光谱(ICOS)设备也被用作光谱参考,以验证大气线的位置。还讨论了 TDLAS 收集系统设计对信噪比(S/N)的影响,以及路径湍流对基线噪声的影响,并为选择受分子吸收影响最小的 DPAL 变体提供了信息。