Ploner Moritz, Wang Ningzhen, Wu Chao, Daniels Robert, Huo Jindong, Sotzing Gregory A, Cao Yang
Electrical Insulation Research Center, Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA.
Department of Chemistry, University of Connecticut, Storrs, CT 06269, USA.
iScience. 2022 Nov 17;25(12):105607. doi: 10.1016/j.isci.2022.105607. eCollection 2022 Dec 22.
All-organic, flexible, and body-compatible loudspeakers have become increasingly attractive for wearable electronics. Due to their remarkable piezoelectric response, ferroelectrets are suitable for loudspeakers. Two distinct kinds of ultrathin ferroelectrets, including cellular polypropylene films and expanded polytetrafluoroethylene (ePTFE) films, were combined with three different types of electrodes ((Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS))-coated fabrics, PEDOT:PSS direct coating, and sputter-coated Au/Pd) for study regarding their frequency-dependent sound intensity and radiation directivity. Among the loudspeakers investigated, the all-fabric loudspeakers with ePTFE ferroelectret and PEDOT:PSS-coated spandex electrodes have a higher frequency dependency. Loudspeakers equipped with PEDOT:PSS-coated spandex electrodes are less angle dependent compared to other loudspeakers evaluated. Moreover, the soft loudspeaker constituted of an all-organic FEP(fluorinated-ethylene-propylene)-ePTFE-based ferroelectret and PEDOT:PSS-coated fabrics presented in this paper is easy to integrate with clothes and has a higher thermal stability. It is naturally compatible with the human body and a competitive candidate for future developments of all-organic loudspeakers for wearable electronic systems.
全有机、柔性且与人体兼容的扬声器对可穿戴电子产品越来越有吸引力。由于其显著的压电响应,铁电驻极体适用于扬声器。两种不同类型的超薄铁电驻极体,包括多孔聚丙烯薄膜和膨化聚四氟乙烯(ePTFE)薄膜,与三种不同类型的电极(聚(3,4-乙撑二氧噻吩):聚(苯乙烯磺酸盐)(PEDOT:PSS)涂层织物、PEDOT:PSS直接涂层和溅射涂层Au/Pd)相结合,以研究它们的频率相关声强和辐射方向性。在所研究的扬声器中,具有ePTFE铁电驻极体和PEDOT:PSS涂层氨纶电极的全织物扬声器具有更高的频率依赖性。与其他评估的扬声器相比,配备PEDOT:PSS涂层氨纶电极的扬声器角度依赖性较小。此外,本文介绍的由全有机氟化乙丙烯(FEP)-ePTFE基铁电驻极体和PEDOT:PSS涂层织物构成的柔性扬声器易于与衣物集成,并且具有更高的热稳定性。它与人体自然兼容,是可穿戴电子系统中全有机扬声器未来发展的有竞争力的候选者。