Instituto Universitario de Ingeniería de Alimentos para el Desarrollo (IUIAD-UPV), Universitat Politècnica de València Camino de Vera s/n, 46022 Valencia, Spain.
REDOLí, Departamento de Química Inorgánica, Universitat de València, 46100 Burjassot, Valencia, Spain.
Food Res Int. 2022 Dec;162(Pt B):112073. doi: 10.1016/j.foodres.2022.112073. Epub 2022 Oct 21.
Fruits and vegetables juices present a high supply of polyphenols, making them highly exposed to enzymatic browning. In this work, we report a novel magnetized mesoporous silica material (FeONPs-UVM-7) functionalised with thiol and amine groups and evaluate their effect on the enzymatic browning as well as the physicochemical properties (pH and °Brix), bioactive compounds (ascorbic acid, total phenolics, flavonoids, and flavonols) and the antioxidant capacity of cloudy apple juice. From the obtained results, the mesoporous silica material magnetized by 11 % (w/w) with magnetite and functionalized with thiol groups reduce by 70 % the enzymatic browning in apple juice. It did not affect the physicochemical parameters such as pH or total soluble solids with respect to freshly squeezed juice. In addition, the content of flavonoids, vitamin C, and the antioxidant capacity measured by ABTS are also not affected by oxidation. However, the total content of polyphenols in the treated juice drops by 15 % compared to freshly squeezed juice, nonetheless, the loss is 20 % less than the control untreated. Thus, the material mitigates the loss of total polyphenols and also the antioxidant capacity.
果蔬汁含有丰富的多酚类物质,因此极易发生酶促褐变。在这项工作中,我们报告了一种新型的功能化磁性介孔硅材料(FeONPs-UVM-7),其表面含有巯基和氨基,并评估了其对酶促褐变的影响,以及对混浊苹果汁的理化性质(pH 值和 °Brix)、生物活性化合物(抗坏血酸、总酚类、类黄酮和黄烷醇)和抗氧化能力的影响。从得到的结果来看,用 11%(w/w)的磁铁矿磁化并巯基功能化的介孔硅材料使苹果汁的酶促褐变减少了 70%。与新鲜压榨的果汁相比,它并没有影响 pH 值或总可溶性固体等理化参数。此外,用 ABTS 测定的类黄酮、维生素 C 和抗氧化能力的含量也不受氧化的影响。然而,与新鲜压榨的果汁相比,处理过的果汁中总多酚的含量下降了 15%,但与未处理的对照果汁相比,损失减少了 20%。因此,这种材料减轻了总多酚和抗氧化能力的损失。