Department of Chemistry and Biotechnology, Tottori University, Tottori, Japan.
Adv Carbohydr Chem Biochem. 2022;82:1-10. doi: 10.1016/bs.accb.2022.10.004. Epub 2022 Nov 10.
In this chapter are described electrochemical routes to cyclic oligosaccharides. While automated electrochemical methods have been used to prepare linear oligosaccharides, their conversion to cyclic oligosaccharides proved to be a complex process. The concept of polyglycosylation offers an interesting alternative, and the process which has been developed is that of a one-pot electrochemical polyglycosylation-isomerization-cyclization (ePIC) process.
本章介绍了环状寡糖的电化学合成途径。虽然自动化电化学方法已被用于制备线性寡糖，但将其转化为环状寡糖被证明是一个复杂的过程。多聚糖化的概念提供了一种有趣的替代方法，所开发的方法是一锅电多聚糖化-异构化-环化（ePIC）过程。
