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具有离子聚芳醚复合膜的燃料电池组件的效率分析

Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane.

作者信息

Wen Hsin-Yi, Wang Guang-Hsiang, Chang Mei-Ying, Huang Wen-Yao, Hsieh Tung-Li

机构信息

Department of Chemical and Materials Engineering, National Kaohsiung University of Science and Technology, Kaohsiung 80778, Taiwan.

Department of Photonics, National Sun Yat-sen University, Kaohsiung 80424, Taiwan.

出版信息

Membranes (Basel). 2022 Dec 7;12(12):1238. doi: 10.3390/membranes12121238.

Abstract

We use polyethylene glycol as an additive to explore how the hydrogen bonding of this additive changes the properties of SA8 blended sulfonated polyetheretherketone (SPEEK) composite films. We mixed a 5%wt polyethylene glycol solution into a 12.5%wt SA8 solution, and then prepared a film with a total weight of 40 g at a ratio of 1:99. The SA8 (PEG) solution was prepared and then mixed with 5%wt SPEEK solution, and a film-forming solution with a total weight of 8g in different mixing ratios was created. Polyethylene glycol (PEG) was mixed into the sulfonated polyarylether polymer SA8 to form physical cross-linking. Therefore, the sulfonated polyether ether ketone SPEEK was mixed in, and it exhibited good thermal stability and dimensional stability. However, there was some decrease in proton conductivity as the proportion of SPEEK increased. Although SPEEK mixed with sulfonated polymer reduces the proton conductivity, the physical cross-linking of PEG can improve the proton conductivity of the composite membrane, and adding SPEEK can not only solve the problem of the high sulfonation film swelling phenomenon, it can also improve the dimensional stability of the film through the hydrogen bonding force of PEG and obtain a composite film with excellent properties.

摘要

我们使用聚乙二醇作为添加剂,以探究该添加剂的氢键如何改变SA8共混磺化聚醚醚酮(SPEEK)复合膜的性能。我们将5%重量的聚乙二醇溶液混入12.5%重量的SA8溶液中,然后以1:99的比例制备了总重量为40克的薄膜。制备了SA8(PEG)溶液,然后与5%重量的SPEEK溶液混合,制得不同混合比例下总重量为8克的成膜溶液。将聚乙二醇(PEG)混入磺化聚芳醚聚合物SA8中形成物理交联。因此,混入了磺化聚醚醚酮SPEEK,其表现出良好的热稳定性和尺寸稳定性。然而,随着SPEEK比例的增加,质子传导率有所下降。虽然SPEEK与磺化聚合物混合会降低质子传导率,但PEG的物理交联可以提高复合膜的质子传导率,并且添加SPEEK不仅可以解决高磺化度膜的溶胀现象问题,还可以通过PEG的氢键力提高膜的尺寸稳定性,从而获得具有优异性能的复合膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c3ec/9781248/6b8bf3e3c265/membranes-12-01238-g001.jpg

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