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非平衡等离子体处理对纺织品的改性机制。

Mechanisms Involved in the Modification of Textiles by Non-Equilibrium Plasma Treatment.

机构信息

Department of Surface Engineering, Jožef Stefan Institute, 1000 Ljubljana, Slovenia.

出版信息

Molecules. 2022 Dec 19;27(24):9064. doi: 10.3390/molecules27249064.

Abstract

Plasma methods are often employed for the desired wettability and soaking properties of polymeric textiles, but the exact mechanisms involved in plasma-textile interactions are yet to be discovered. This review presents the fundamentals of plasma penetration into textiles and illustrates mechanisms that lead to the appropriate surface finish of fibers inside the textile. The crucial relations are provided, and the different concepts of low-pressure and atmospheric-pressure discharges useful for the modification of textile's properties are explained. The atmospheric-pressure plasma sustained in the form of numerous stochastical streamers will penetrate textiles of reasonable porosity, so the reactive species useful for the functionalization of fibers deep inside the textile will be created inside the textile. Low-pressure plasmas sustained at reasonable discharge power will not penetrate into the textile, so the depth of the modified textile is limited by the diffusion of reactive species. Since the charged particles neutralize on the textile surface, the neutral species will functionalize the fibers deep inside the textile when low-pressure plasma is chosen for the treatment of textiles.

摘要

等离子体方法常用于获得聚合物纺织品所需的润湿性和浸渍性能,但等离子体与纺织品相互作用的确切机制仍有待发现。本文综述了等离子体渗透到纺织品中的基本原理,并说明了导致纤维在纺织品内部获得适当表面整理的机制。提供了关键关系,并解释了用于改变纺织品性能的低压和常压放电的不同概念。以大量随机流光的形式维持的常压等离子体将渗透到具有合理孔隙率的纺织品中,因此,在纺织品内部将产生对纤维进行功能化的有用反应性物质。以合理的放电功率维持的低压等离子体不会渗透到纺织品中,因此,当选择低压等离子体处理纺织品时,改性纺织品的深度受反应性物质扩散的限制。由于带电粒子在纺织品表面上中和,因此当选择低压等离子体处理纺织品时,中性物质将对纺织品内部深处的纤维进行功能化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b3a4/9780991/22ad1a54385e/molecules-27-09064-g001.jpg

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