苹果潜叶蛾（Lyonetia prunifoliella）性信息素的不对称合成

Asymmetric synthesis of the sex pheromone of the apple leafminer, Lyonetia prunifoliella.

作者信息

Yu Shihang, Yuan Gucheng, Liu Jiawei, Bian Qinghua, Wang Min, Zhong Jiangchun

机构信息

Department of Applied Chemistry, China Agricultural University, Beijing, China.

出版信息

Chirality. 2023 Feb;35(2):118-128. doi: 10.1002/chir.23524. Epub 2022 Dec 27.

DOI:10.1002/chir.23524

PMID:36573613

Abstract

Lyonetia prunifoliella is a significant pest in orchards and damages apple. The sex pheromones of this pest were prepared via a new and concise method. The central to our method were Evans' chiral auxiliaries, the addition of chiral Grignard reagent to aldehyde and Wittig coupling.

摘要

李枯叶蛾是果园中的一种重要害虫，会对苹果造成损害。这种害虫的性信息素是通过一种新的简洁方法制备的。我们方法的核心是埃文斯手性助剂、手性格氏试剂与醛的加成反应以及维蒂希偶联反应。